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3
votes
1answer
90 views

Fick's first law inhomogeneous proof

I have seen Fick's first law of diffusion derived for a homogeneous material many times, however I am struggling to find a satisfactory proof for inhomogeneous, particularly for particle diffusion. ...
2
votes
1answer
36 views

Thermal healing of defects in crystals

Thermal treatment can heal point defects due to the diffusion of atoms towards empty points. In a solid crystal structure, atoms do not diffuse at room temperature (correct?) Energy of thermal ...
7
votes
0answers
215 views

Diffusion of gases in the atmosphere

Suppose that the atmosphere is composed of 21% $O_2$ and 78% $Kr$ (instead of $N_2$). Since the density of $Kr$ is greater than the density of $O_2$, the lower atmosphere (where we live) should be ...
5
votes
0answers
80 views

Green's function for moving solidification front

Consider a liquid solid interface $z =\zeta(x,t)$ moving at constant speed $v$, for a two dimensional problem. Due to solidification interface is changing it position. For simplicity heat ...
4
votes
0answers
58 views

Stochastic process generating fractional diffusion

One way to generate Brownian motion is as follows: Define a waiting time probability distribution $\psi(t)$ and step length probability distribution $\lambda(x)$. Require also that $\langle \psi ...
2
votes
0answers
32 views

What physical processes govern the formation and shape of clouds?

There are many kinds of cloud shapes that appear in the sky. In fact, it's not unusual to see several different kinds of clouds in the same sky. What kind of physics equations and processes govern ...
2
votes
0answers
24 views

Random walk with self-transitions taking continuum limit

does anyone have any suggestions regarding how to correctly treat the continuum limit of a random walk that has non-zero self-transition probabilities? To put this concretely, let's say that the ...
2
votes
0answers
52 views

Is the diffusion coefficient time-dependent?

It is known that in the partial differential equation: $$u_t=au_{xx} $$ within the limits $0<x<1$ and $a>0$, the diffusion coefficient, arises in the mathematical modelling of a process of ...
2
votes
0answers
253 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
2
votes
0answers
186 views

Diffussivity of gases, molecular weight and Lewis number

I am trying to understand the following figure of laminar premixed flames: The Lewis number is defined as $Le = \frac{\alpha_{mix}}{D_{fuel}}$ where $\alpha_{mix}$ is the thermal diffusivity of ...
1
vote
0answers
14 views

can 3D diffusion be interpreted as superposition of 1D diffusion

Is diffusion of a substance in water independent in the X, Y and Z directions? In other words, if I want to solve how a substance diffuses through a volume, can I separately solve equations for its ...
1
vote
0answers
13 views

Diffusion of magnetization (NMR)

In the context of MRI I'm trying to understand the mechanisms of magnetization diffusion. Consider a sample that is magnetized by an external magnetic field. We have displacement of magnetic moment ...
1
vote
0answers
63 views

Riemannian generalization/adaption of the Hubbard–Stratonovich transformation

I'd like to write the Hubbard–Stratonovich (HS) transformation of a scalar function on a Riemannian manifold. This transformation is quite simple in Euclidean space. One can consider it as a Fourier ...
1
vote
0answers
65 views

How do I apply a renormalization technique to estimate the fractal dimension of a diffusion limited aggregate?

Diffusion Limited Aggregation (DLA) is an interesting phenomena observed in nature and discussed here. From a theoretical view point, it'd be nice to know about the fractal dimension of a DLA formed ...
1
vote
0answers
83 views

How does fluid velocity affect the dissolution of some solute in the fluid?

Suppose we have a perfect sphere of some solute such as sugar and we place it in a fluid such as water, at a certain temperature, that is not moving. It will dissolve and diffuse into the water due to ...
1
vote
0answers
57 views

Contradiction (?): DNA ion mobility vs diffusion constant

There is a certain confusion about DNA ion mobility and diffusion constant in the literature. Consider double-stranded DNA ions in pure water. DNA ions are negatively charged due to phosphoric acid ...
1
vote
0answers
34 views

What is a diffusionless fluid?

I'm taking a course in astrophysical fluid dynamics and have come across a problem involving "small diffusionless disturbances" of a fluid. Based on the nature of the course I expect the examiner to ...
1
vote
0answers
56 views

In the process of Diffusion Limited Aggregation (DLA), why do the particles prefer to form something which has the shape of a tree?

In the process of Diffusion Limited Aggregation (DLA), why do the particles prefer to form something which has the shape of a tree instead of just a front line?
1
vote
0answers
83 views

Analytic solution to diffusion in composite medium for long times

I am trying to find an analytical solution to the transient 1D diffusion equation in a composite medium (e.g. binary liquid): $$\partial_t c_i = D\partial_x^2 c_i$$ where the domain for species $i$ is ...
1
vote
0answers
464 views

How can one calculate diffusion velocity given the diffusion coefficient?

I am creating a basic simulation of 2-D diffusion and was wondering how diffusion velocity of a particle can be calculated if the diffusion coefficient is known (using no other information). Is this ...
1
vote
0answers
68 views

Why is it valid to assume that the liquid-vapour interface is always saturated during evaporation?

For steady state evaporation, I read from two textbooks which simply states that the partial pressure of vapour of interest (say water) at the liquid-vapour interface is equal to the saturation ...
1
vote
0answers
77 views

Is phase defined for species undergoing diffusion?

If we have a gas diffusing through say a solid metal, or gas diffusing into a liquid, what phase is the diffusing molecules considered to be in (or is it even possible to define this)? Is it possible ...
1
vote
0answers
25 views

Conventional flux in centrifuge?

The molecules sediment in centrifuge, which is rotating with angular velocity $\omega$. The chemical potential of molecule (considering potential associated with centrifuge force) is: ...
1
vote
0answers
64 views

Diffusion of particles

If $n(\vec{r},t)$ is the number of particles per unit volume and $V$ the volume, then $N = nV $is the number of particles in volume $V$ For a small volume, it should be $dN = d(nV) = Vdn + ndV$ But ...
1
vote
0answers
69 views

Validity of a steady state solution of reaction-diffusion equation

I am performing a simulation involving growth of bacteria. This is an agent-based simulation where the solutes (glucose, oxygen etc.) are represented as a concentration field discretised over space, ...
1
vote
0answers
37 views

Solid state diffusion as a function of shear stress

I am hoping to get some clarification on the impact of shear stress or shear strain on atomic diffusion in a metallic solid. More specifically, will the kinetics for the dissolution of secondary phase ...
1
vote
0answers
163 views

Leakage rate Calculation

I have to calculate leak rate for helium/air from an enclosure which is made of fabric. This is similar to helium balloons. There are small holes in the fabric. How should i proceed ?
1
vote
0answers
85 views

Concentration of Proteins

You release a billion protein molecules at position $x = 0$ in the middle of a narrow capillary test tube. The molecules’ diffusion constant is $10^{−6} \ cm^2 s^{−1}$. An electric field pulls ...
1
vote
0answers
232 views

Mechanical effects of convective flow in steady-state stagnant film diffusion

When analysing diffusion problems in the context of the simplified film model, two limiting cases are ussually introduced during the solution of the differential chemical species mass balance ...
0
votes
0answers
45 views

Does nature really follow the heat equation?

I think the heat equation says that the first derivative of temperature with respect to time in a stationary solid varies as the negative of the second derivative of temperature with respect to ...
0
votes
0answers
13 views

Extension of the advection diffusion equation with diffusion perpendicular to the flow

Assume you model particle flow in fluid in a cylinder by an advection-diffusion equation, thus taking into account both diffusion and bulk flow. What would happen to the model if you would, at some ...
0
votes
0answers
25 views

trying to figure out an expansion in Brownian motion derivation

In the derivation for the diffusion equation on the wikipedia article for Brownian motion, they have these equations: I can't figure out how $\rho(x+\Delta,t)$ gets expanded, though. For a Taylor ...
0
votes
0answers
31 views

The change in time of a concentration in a fluid can be described by Reynolds' theorem. Is that the whole story?

Let $d\in\left\{2,3\right\}$ and $\Omega_t\subseteq\mathbb R^d$ be the bounded set occupied by a fluid at time $t\ge 0$. Moreover, let $\eta_t:\Omega_t\to[0,\infty)$ be the concentration of imaginary ...
0
votes
0answers
15 views

Fluid flow in porous medium with moving boundary

Everyone, I would like to numerically model axisymmetric fluid flow in a porous medium with a moving boundary, where the fluid pressure is specified on the boundary, whose radius increases with time. ...
0
votes
0answers
31 views

Is it possible that my 750ml water bottle contains spent fuel from a space shuttle launch

Firstly I live in New Zealand which is very distant from USA which is where the space shuttle was originally launched from. So what is the possibility of molecules from the rocket engines spent ...
0
votes
0answers
43 views

How long does it take for an Oxygen to diffuse around Earth?

We drill into the ground and find a huge pocket of oxygen. How long does it take for that oxygen to diffuse around Earth? I'd like to know for the first oxygen molecule how long it takes to effect the ...
0
votes
0answers
36 views

How can I get the boundary and initial conditions of the convection–diffusion equation consistant?

I want to solve the 1D convection–diffusion equation. The boundary conditions are a flux in from the bottom and a flux out on the top. Furthermore I want no concentration inside at the beginning. I ...
0
votes
0answers
53 views

Confusion regarding interpretation of a diffusion related PDE?

So I was reading Keller & Segel paper related to mathematical model of cellular aggregation in slime molds. In the model (considering 2D assumption) we have an equation like below: ...
0
votes
0answers
111 views

1D drift-diffusion equation with single absorbing boundary

If we have just the simple diffusion equation (in 1D): $$ \frac{\partial P(x,t)}{\partial t} = D \frac{\partial^2 P(x,t)}{\partial x^2} $$ with an absorbing boundary at x=0 and initial condition ...
0
votes
0answers
52 views

Anomalous diffusion dynamic exponent calculation

I'm trying to calculate this $\alpha$ (dynamic exponent, I think) from an equation from this wikipedia article. The equation (anomalous diffusion power law): $r^2 \propto t^\alpha$ The problem is ...
0
votes
0answers
25 views

How to calculate diffusion lenghth in a constant source and sink model?

Here is the context: in 1D, a pathogen cell sits in a homogenous bath of antibiotic. It can express a protein that destroy the antibiotic molecule to protect itself. Given the concentration of ...
0
votes
0answers
100 views

Derivation of diffusion coefficient

For diffusion transport considering the "random walk" of electrons, I have the following derivation that leads to the diffusion coefficient $D$: $$d_1=d_2=\dots=d_n=\tau v \implies\\ \sum_n ...
0
votes
0answers
47 views

Ratio between thermal conductivity heat transfer coefficient

Consider the Robin boundary condition for the diffusion/heat equation $u_t=a(t)u_{xx}+f(x,t)$: $$\mathrm{-k(t)u_x(0,t)=h(t)u(0,t)}$$ or $$\mathrm{u_x(0,t)+\frac{h(t)}{k(t)}u(0,t)=0}$$ where ...
0
votes
0answers
70 views

Modelling the diffusion of gas in a container with non uniform temperature

I want to model diffusion of a gas (e.g. water vapor diffusion in air) in a container with a temperature gradient. One side of the container has a hole, but for simplicity of boundary conditions I can ...
0
votes
0answers
50 views

Mathematical Model For Osmosis

We already know that physical phenomena like diffusion could be modelled using PDEs. For example, denoting the concentration by $u$, the diffusion process reads: $$ \partial_t{u} = \Delta{u} $$ Now my ...
0
votes
0answers
55 views

Martensitic transformation in ceramics

What is the specification of Martensite (displacive) transformation in ceramics comparing to yhe one in metals? I just know about Martensite transformation in metals. For example, these ...
0
votes
0answers
226 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
0
votes
0answers
44 views

Deriving diffusion coefficients from velocity field?

If I know the velocity, $\mathbf{v}(\mathbf{r},t)$, everywhere, is it possible to determine the diffusion coefficient, $D(\mathbf{r},t)$ everywhere as well? Would it be possible from using Fick's ...
0
votes
0answers
51 views

Should particles in Smoothed Particle Hydrodynamics (SPH) always move during a simulation?

Or can they just be used as an interpolation points and use some other "transported property" which are just evolved and propagated from boundary conditions like for eg. heat conduction through a ...
0
votes
0answers
68 views

Ask for help: the Reaction-Diffusion related problem

In container there are two kinds of molecules A and B which are distributed uniformly. Initially the quantities of A and B are $N_A$ and $N_B$ respectively A and B are distributed uniform, i.e., in ...