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Behaviour of Gases [on hold]

Gases tend to move from higher pressure to lower pressure, thats fine. But why they are so aggressive in this regard. For example, in vacuum-lifters they are able to lift mass (weight) of up-to ...
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1answer
30 views

Heat diffusion equation with time dependent specific heat capacity

What is the correct form of the heat diffusion equation in 1D if we take into account the temperature dependency of specific heat capacity? $$ \rho\frac{d(cT)}{dt} = ...
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Is the diffusion coefficient time-dependent?

It is known that in the partial differential equation: $$u_t=au_{xx} $$ within the limits $0<x<1$ and $a>0$, the diffusion coefficient, arises in the mathematical modelling of a process of ...
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1answer
99 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
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1answer
2k views

What is the difference between the words transparent and translucent?

Merriam Webster defines transparent as: Having the property of transmitting light without appreciable scattering so that bodies lying beyond are seen clearly. And translucent as: ...
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2answers
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Convective and Diffusive terms in Navier Stokes Equations

My question has 2 parts: I just followed the derivation of Navier Stokes (for Control Volume CFD analysis) and was able to understand most parts. However, the book I use (by Versteeg) does not ...
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1answer
94 views

Time for a particle undergoing brownian motion to reach a point in a volume

I was wondering how one could calculate the average time a particle needs to reach a random point in a small sphere (filled by water) with a radius of maybe $10 \mu m$. I thought of using the ...
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4answers
98 views

Why doesn't fire flow back INTO the cylinder?

Let us take into a consideration a (pressurized) kerosene stove. The pressure drives fuel out of the nozzle, like or in a much simpler arrangement as in Question- Why doesn't fire flow back ...
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2answers
325 views

Existence of gusts of wind, an anomaly?

Enthusiast + Student, not a pro, so pardon my ignorance. How can wind possibly flow in gusts? The way I understand it, a gust is a pocket of air which hits you at slightly higher speed. But how ...
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1answer
22 views

Getting the velocity of self-diffusion from the einstein relation

I have been reading about self-diffusion of a particle here: http://www-hsc.usc.edu/~rfarley/Diffusion-SI-2003.pdf and on page 9 it gives Einstein's relation as $(\Delta x)^2 = 2 D t$ and I can ...
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2answers
37 views

Why do the free electrons in N-type want to diffuse?

I'm trying to understand how a diode works and for this I've used(among other resources) the book written by Albert Malvino, Electronic Principles. Everywhere I read about this topic, it says that ...
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3answers
63 views

What is the exact difference between diffusion, convection and advection?

I have tried to explore the information but still not very clear on the exact difference between diffusion, convection and advection. Can anyone help me out to clear my concept?
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59 views

Standard partial differential equation? [migrated]

Is there any standard equation which looks like this one, $$ u_{t}(x,t) = \alpha \, u_{xx}(x,t) - \beta(t) \, u(x,t) + S(x,t), $$ where $\beta(t)$ is nonlinear in time, and $\alpha$ is a constant? ...
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1answer
70 views

How does a minority carrier diffuse?

I have gone through a lot of questions but none of them ask how do the minority carriers approach the depletion layer in the first place. When a p-n junction is formed, negative space charge ...
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3answers
56 views

Force causing diffusion

I was curious if there was an equation describing the force acting on a particle (say, sitting in a fluid) that causes it to diffuse. If so, does it include the diffusion coefficient D? Based on ...
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1answer
628 views

How fast will sublimed dry ice mix with air?

I saw this photo and wondered: Will the CO2 stay mostly in a layer on the floor with the rest of the atmosphere resting on top, or will it quickly diffuse throughout the room? This lab is probably ...
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1answer
42 views

What is the difference between the diffusion equation and the heat equation?

I know that the diffusion equation is a more general version of the heat equation. But what is the exact difference informally?
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1answer
54 views

Does water diffuse trough rubber of car tire of when liquid or only as gas

Does Water difuse trough rubber of car tire when its liquid or only when its a gas. Can also be that is diffuses but slower when liqiud. I want to know this for my argumentation that filling car tire ...
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0answers
33 views

Mathematical Model For Osmosis

We already know that physical phenomena like diffusion could be modelled using PDEs. For example, denoting the concentration by $u$, the diffusion process reads: $$ \partial_t{u} = \Delta{u} $$ Now my ...
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2answers
137 views

Can diffusion produce energy?

A friend and I recently got into a silly argument where I stated pure diffusion can't produce energy since diffusion are a part of passive transport. He stated if we If we have tinny ...
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0answers
25 views

Heat sink simulation with a fan

I am trying to solve this problem using advection-diffusion model and finite element method for solving it due to the complex geometry. Basically the problem i'm trying to solve using OpenFOAM is see ...
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0answers
67 views

Green's function for moving solidification front

Consider a liquid solid interface $z =\zeta(x,t)$ moving at constant speed $v$, for a two dimensional problem. Due to solidification interface is changing it position. For simplicity heat ...
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0answers
68 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
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1answer
35 views

Reaction-diffusion. From kinetic parameters in 3D, can we infer their equivalent in 1D?

I am studying a reaction-diffusion system : $A+B ⇌_{k_{-}}^{k_{+}} C$. From experimental data I have all the kinetic parameters : diffusion coefficients $d$ and reaction rates $k_+$, $k_-$. Beside I ...
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0answers
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Analytic solution to diffusion in composite medium for long times

I am trying to solve the transient 1D diffusion equation in a composite medium where the interfacial concentration is described by a Henry condition. I have found an adequate solution for short times ...
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0answers
42 views

How can one calculate diffusion velocity given the diffusion coefficient?

I am creating a basic simulation of 2-D diffusion and was wondering how diffusion velocity of a particle can be calculated if the diffusion coefficient is known (using no other information). Is this ...
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0answers
21 views

Diffusion modeled by Levy process and Wiener process

I'm reading about diffusion and see that both Levy process and Wiener process can be used to model the diffusion of a particle. Why Levy process is more general than Wiener process, especially in term ...
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0answers
30 views

Martensitic transformation in ceramics

What is the specification of Martensite (displacive) transformation in ceramics comparing to yhe one in metals? I just know about Martensite transformation in metals. For example, these ...
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1answer
108 views

Heat diffusion: evanescent waves?

It has been recently pointed out to me that the solution of the heat equation in a semi-infinite material with an oscillating boundary condition at the surface is not an evanescent wave. The argument ...
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1answer
18 views

Dynamic equations for propagation of light through dust

For smoothly inhomogeneous media light propagation can be modeled by Maxwell's equations with non-constant $\varepsilon$ and $\mu$. This allows to relatively easily model propagation in the medium ...
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2answers
40 views

Energy Flux due to Diffusion

Per the Fundamental Thermodynamic Relation, I know that the chemical potential of $i$ represents the energy which would added to a system if a particle of $i$ were added with all other system ...
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3answers
9k views

What is the physical meaning of diffusion coefficient?

In Fick's first law, the diffusion coefficient is velocity, but I do not understand the two-dimensional concept of this velocity. Imagine that solutes are diffusing from one side of a tube to another ...
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1answer
148 views

Rate of Temperature Change due to Heat addition

I might be wrong but I will give a little background leading to my question. I am trying to calculate the heat generation in the advection-diffusion equation for heat generation due to friction by ...
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1answer
108 views

Everyday example of diffusion unobscured by advection, wetting etc

Diffusion is an important concept in elementary science education, especially because it supports (or seems to support) the notion of matter consisting of very small everyday particles (as opposed to ...
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3answers
308 views

Schrödinger equation derivation and Diffusion equation

I am aware of the debate on whether Schrödinger equation was derived or motivated. However, I have not seen this one that I describe below. Wonder if it could be relevant. If not historically but for ...
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35 views

Why is it valid to assume that the liquid-vapour interface is always saturated during evaporation?

For steady state evaporation, I read from two textbooks which simply states that the partial pressure of vapour of interest (say water) at the liquid-vapour interface is equal to the saturation ...
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0answers
40 views

Is phase defined for species undergoing diffusion?

If we have a gas diffusing through say a solid metal, or gas diffusing into a liquid, what phase is the diffusing molecules considered to be in (or is it even possible to define this)? Is it possible ...
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0answers
12 views

Conventional flux in centrifuge?

The molecules sediment in centrifuge, which is rotating with angular velocity $\omega$. The chemical potential of molecule (considering potential associated with centrifuge force) is: ...
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1answer
19 views

Thermal healing of defects in crystals

Thermal treatment can heal point defects due to the diffusion of atoms towards empty points. In a solid crystal structure, atoms do not diffuse at room temperature (correct?) Energy of thermal ...
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0answers
54 views

Diffusion of particles

If $n(\vec{r},t)$ is the number of particles per unit volume and $V$ the volume, then $N = nV $is the number of particles in volume $V$ For a small volume, it should be $dN = d(nV) = Vdn + ndV$ But ...
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1answer
29 views

How big are soluted salts in drinking water?

I have just seen the TED talk Michael Pritchard: How to make filthy water drinkable where a device called LifeSaver bottle that filters particles that are bigger than 15nm out of water. I have heard ...
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1answer
762 views

Understanding the mean square displacement in molecular dynamics

In a Molecular Dynamics (MD) simulation, the mean square displacement $\text{MSD}$ is given by $$\text{MSD}(\delta t) = \left\langle\left|\vec{r}(\delta t)-\vec{r}(0)\right|^2\right\rangle,$$ where ...
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1answer
42 views

How do I set up the tridiagonal matrix for a heat diffusion with layers of different thermal diffusivity?

I have Scala code that recreates the Crank-Nicolson solutions for the diffusion equations, and matches 'Excel for Scientists and Engineers' (Joe Billo, Wiley). However, I would like to be able to ...
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0answers
89 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
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3answers
41k views

Surviving under water in air bubble

An incredible news story today is about a man who survived for two days at the bottom of the sea (~30 m deep) in a capsized boat, in an air bubble that formed in a corner of the boat. He was ...
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1answer
2k views

Characteristic length for the diffusion equation (temperature)

The background: I'm doing some simulation work involving the diffusion equation in 1D. Specifically I have some temperature profile, constant thermal conductivity and fixed temperature at each end of ...
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1answer
211 views

Why viscosity is diffusive?

I'm studying fluid mechanics in more depth during my Ph. D. and there is something related with the diffusive term that has been bothering me for a long time. Looking at the convection diffusion ...
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2answers
168 views

Where I can find information about how helium gas diffuses through different polymer materials

I need more experimental information about helium gas diffusion in solid materials such as different plastics, metals, ceramics etc. For example I am scientifically curious about what is the polymer ...
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1answer
84 views

Diffusion in the standard map

Consider the standard map (also known as Chirikov map): $$ p_{n+1} = p_n + K \sin(\theta_n) \\ \theta_{n+1} = \theta_n + p_{n+1} $$ I know that the diffusion coefficient according to the ...
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1answer
156 views

Does QED provide a closed form for Coulomb logarithms?

The classical models for the integrand as well as the cut-offs in computing the Coulomb logarithm are pretty rough. Does quantum electrodynamics have definite expressions for the quantity ...