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1answer
45 views

Time for a particle undergoing brownian motion to reach a point in a volume

I was wondering how one could calculate the average time a particle needs to reach a random point in a small sphere (filled by water) with a radius of maybe $10 \mu m$. I thought of using the ...
-2
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0answers
14 views

Diffusion Equation [closed]

Please give me some guidance on my following assignment of Simulations in fluid flow: Thank you. Solve the following differential equation for transport of f(x,y,z,t) by MS Excel ∂f/∂t+Ux ∂f/∂x+Uy ...
1
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1answer
33 views

Rate of Temperature Change due to Heat addition

I might be wrong but I will give a little background leading to my question. I am trying to calculate the heat generation in the advection-diffusion equation for heat generation due to friction by ...
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0answers
14 views

Does water diffuse trough rubber of car tire of when liquid or only as gas

Does Water difuse trough rubber of car tire when its liquid or only when its a gas. Can also be that is diffuses but slower when liqiud. I want to know this for my argumentation that filling car tire ...
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3answers
114 views

Schrödinger equation derivation and Diffusion equation

I am aware of the debate on whether Schrödinger equation was derived or motivated. However, I have not seen this one that I describe below. Wonder if it could be relevant. If not historically but for ...
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0answers
30 views

Why is it valid to assume that the liquid-vapour interface is always saturated during evaporation?

For steady state evaporation, I read from two textbooks which simply states that the partial pressure of vapour of interest (say water) at the liquid-vapour interface is equal to the saturation ...
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0answers
31 views

Is phase defined for species undergoing diffusion?

If we have a gas diffusing through say a solid metal, or gas diffusing into a liquid, what phase is the diffusing molecules considered to be in (or is it even possible to define this)? Is it possible ...
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0answers
10 views

Conventional flux in centrifuge?

The molecules sediment in centrifuge, which is rotating with angular velocity $\omega$. The chemical potential of molecule (considering potential associated with centrifuge force) is: ...
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0answers
47 views

Diffusion of particles

If $n(\vec{r},t)$ is the number of particles per unit volume and $V$ the volume, then $N = nV $is the number of particles in volume $V$ For a small volume, it should be $dN = d(nV) = Vdn + ndV$ But ...
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1answer
28 views

How big are soluted salts in drinking water?

I have just seen the TED talk Michael Pritchard: How to make filthy water drinkable where a device called LifeSaver bottle that filters particles that are bigger than 15nm out of water. I have heard ...
1
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1answer
18 views

How do I set up the tridiagonal matrix for a heat diffusion with layers of different thermal diffusivity?

I have Scala code that recreates the Crank-Nicolson solutions for the diffusion equations, and matches 'Excel for Scientists and Engineers' (Joe Billo, Wiley). However, I would like to be able to ...
0
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0answers
43 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
2
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1answer
14 views

Thermal healing of defects in crystals

Thermal treatment can heal point defects due to the diffusion of atoms towards empty points. In a solid crystal structure, atoms do not diffuse at room temperature (correct?) Energy of thermal ...
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0answers
17 views

Green's function for moving solidification front

Consider a liquid solid interface $z =\zeta(x,t)$ moving at constant speed $v$, for a two dimensional problem. Due to solidification interface is changing it position. For simplicity heat ...
2
votes
1answer
61 views

Diffusion in the standard map

Consider the standard map (also known as Chirikov map): $$ p_{n+1} = p_n + K \sin(\theta_n) \\ \theta_{n+1} = \theta_n + p_{n+1} $$ I know that the diffusion coefficient according to the ...
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2answers
97 views

Where I can find information about how helium gas diffuses through different polymer materials

I need more experimental information about helium gas diffusion in solid materials such as different plastics, metals, ceramics etc. For example I am scientifically curious about what is the polymer ...
1
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0answers
46 views

Validity of a steady state solution of reaction-diffusion equation

I am performing a simulation involving growth of bacteria. This is an agent-based simulation where the solutes (glucose, oxygen etc.) are represented as a concentration field discretised over space, ...
1
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1answer
51 views

1D Smoluchowski diffusion equation in a linear potential

I am interested in solving a 1D Smoluchowski diffusion equation in a linear potential $U(x) = cx$ for a constant force $c$. This problem follows chapter 4 of the theoretical biophysics script by ...
0
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1answer
51 views

How does a minority carrier diffuse?

I have gone through a lot of questions but none of them ask how do the minority carriers approach the depletion layer in the first place. When a p-n junction is formed, negative space charge ...
1
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1answer
83 views

Can diffusion produce energy?

A friend and I recently got into a silly argument where I stated pure diffusion can't produce energy since diffusion are a part of passive transport. He stated if we If we have tinny ...
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2answers
43 views

optical diffusion (scattering) versus refraction

When an electromagnetic wave meets an interface a part of it is reflected and part of it is refracted (and from the refractive index I can calculate the angles of propagation and the intensities using ...
1
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1answer
318 views

Understanding the mean square displacement in molecular dynamics

In a Molecular Dynamics (MD) simulation, the mean square displacement $\text{MSD}$ is given by $$\text{MSD}(\delta t) = \left\langle\left|\vec{r}(\delta t)-\vec{r}(0)\right|^2\right\rangle,$$ where ...
2
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1answer
69 views

Heat diffusion: evanescent waves?

It has been recently pointed out to me that the solution of the heat equation in a semi-infinite material with an oscillating boundary condition at the surface is not an evanescent wave. The argument ...
1
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1answer
73 views

A simple osmosis problem

The following is adapted from a problematic question* asked on the Bio site. I would like to ask it free of those distractions here. If there is anything unduly artificial about the problem please ...
1
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1answer
88 views

Gillespie's stochastic framework valid for particles in aqueous solution?

Gillespie proposed a stochastic framework for simulating chemical reactions which is predicated on non-reactive elastic collisions serving to 'uniformize' particle position so that the assumption of ...
4
votes
1answer
132 views

Simple question regarding the Green's function for the diffusion equation

The differential operator for diffusion in three dimensions is given by $\partial_t - k \nabla^2$ where $k$ is a constant. The Green's function is (according to Wikipedia) $$\theta(t)\left( ...
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4answers
427 views

Do particle velocities in liquid follow the Maxwell-Boltzmann velocity distribution?

The Maxwell-Boltzmann velocity distribution arises from non-reactive elastic collisions of particles and is usually discussed in the context of the kinetic theory (for gases). There are various ...
-1
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1answer
128 views

Boundary conditions for the heat equation when solving a mass density gradient

I'm working with a mass density gradient with length $L$ and I'm trying to solve the heat equation in 1-D (mass diffusion equation, $\partial_t\rho(t,x)=D\Delta\rho(t,x)$), but I'm not sure which ...
1
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1answer
751 views

Characteristic length for the diffusion equation (temperature)

The background: I'm doing some simulation work involving the diffusion equation in 1D. Specifically I have some temperature profile, constant thermal conductivity and fixed temperature at each end of ...
3
votes
1answer
76 views

Spin drift velocity?

I am currently reading this Phys Rev paper by H C Torrey. In this paper, he derives the Bloch equations with an additional diffusion term. He says that the current density is given by $$\mathbf ...
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0answers
81 views

First passage time of diffusing particle with partially absorbing boundary

Given the solution to the spatiotemporal evolution of a single particle on a 1-D surface $P(x,t)$ a nice result (that I gleaned elsewhere on physics.SE) is that for a boundary at $x=0$ where ...
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0answers
31 views

Deriving diffusion coefficients from velocity field?

If I know the velocity, $\mathbf{v}(\mathbf{r},t)$, everywhere, is it possible to determine the diffusion coefficient, $D(\mathbf{r},t)$ everywhere as well? Would it be possible from using Fick's ...
2
votes
1answer
49 views

Rate of probability loss from absorbing boundary

The following is the solution to the 1D diffusion equation with diffusion coefficient D, initial particle position $x_0$, and a perfectly absorbing boundary at $x=0$ (s.t. $P(x=0)=0$). $$ ...
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0answers
49 views

Interpretation of Einstein relation in kinetic theory

I am reviewing my (independent) study notes on diffusion and found the following comment preceding the derivation of the Einstein relation: Now, since the particles that deliver the stochastic ...
2
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1answer
2k views

What is the difference between dispersion and diffusion?

What is the difference between dispersion and diffusion? Currently I believe, that diffusion is the mixture of molecules due to Brownian motion. So I read everywhere, that it happens with magnitude of ...
0
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0answers
34 views

Textbook on Diffusion and Diffusion NMR Spectroscopy

I am looking for textbooks ( Mathematical / Theoretical Physics ) that cover diffusion in general. Although it is not necessary that your recommendation covers it, I am also particularly interested ...
2
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0answers
68 views

Diffussivity of gases, molecular weight and Lewis number

I am trying to understand the following figure of laminar premixed flames: The Lewis number is defined as $Le = \frac{\alpha_{mix}}{D_{fuel}}$ where $\alpha_{mix}$ is the thermal diffusivity of ...
3
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1answer
133 views

Why viscosity is diffusive?

I'm studying fluid mechanics in more depth during my Ph. D. and there is something related with the diffusive term that has been bothering me for a long time. Looking at the convection diffusion ...
1
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1answer
47 views

Can you equate the diffusivity constant in random walks with the one in Brownian motion (Einstein relation)?

In an unbiased random walk in one dimension, the coefficient of diffusion is $D = l^2/2\tau$, where $l$ is the size of the jump and $\tau$ is time taken for that jump. In simple Brownian motion, ...
2
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2answers
205 views

Units of the Stokes-Einstein rotational diffusion coefficient

The Stokes-Einstein rotational diffusion relation tells us that we can write down a rotational diffusion coefficient for a sphere as: $$D_r \approx \frac{k_B T}{\zeta_f} \approx \frac{k_B T}{(8 \pi ...
4
votes
3answers
245 views

Physical interpretation of the change of diffusion term in navier stokes equations

In the Navier-Stokes Equations, there is one term accounting for convective flow and one term for diffusive flow. At high flow rates, the diffusive term becomes much smaller compared to convective ...
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0answers
84 views

Determining The Coefficient of Viscosity and Diffusivity in an Estuary?

I am curious and eager to discuss about the experience of determining viscosity and diffusivity coefficient for our coastal or estuary model. I myself, just start to use the range of: ...
0
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0answers
48 views

Diffusion coefficient of a crystal

I've been trying to work this out so I can give a hand waving argument for one of the effects I'm observing on the fly and I find myself going down a rabbit hole that seems way too complicated for ...
1
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0answers
23 views

Solid state diffusion as a function of shear stress

I am hoping to get some clarification on the impact of shear stress or shear strain on atomic diffusion in a metallic solid. More specifically, will the kinetics for the dissolution of secondary phase ...
0
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2answers
80 views

Simulating diffusion from bulk to individual particles

I have a 2 compartment simulation. The first compartment simulates reactions using ODEs. The second compartment uses Brownian motion. I want to be able to have molecules from the ODE compartment ...
4
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1answer
882 views

What is the difference between the words transparent and translucent?

Merriam Webster defines transparent as: Having the property of transmitting light without appreciable scattering so that bodies lying beyond are seen clearly. And translucent as: ...
1
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1answer
182 views

Temperature rate of change inside a cylinder

I was wondering about this today, mainly for baking a cylindrical cake. Say you have a solid cylinder which is at temperature T0 inside. Say you then move the ...
1
vote
1answer
166 views

How does air escape from a pneumatic tire?

Obviously, it is caused by the difference in pressure between the inside of the tire and its surrounding environment; but how specifically is the air escaping?
0
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0answers
36 views

Should particles in Smoothed Particle Hydrodynamics (SPH) always move during a simulation?

Or can they just be used as an interpolation points and use some other "transported property" which are just evolved and propagated from boundary conditions like for eg. heat conduction through a ...
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2answers
124 views

Counting of brownian particles: Point Process

Imagine a point process defined by the passage time of purely brownian particles through a given point (in 1D), line (2D) or plane (3D). I'm interested in the variance of the counts (number of ...