1
vote
1answer
82 views

Can anyone explain the idea behind dS ∝ dV/V?

In a lecture on entropy, one of the equations $dS ∝ \frac {dV}{V}$ was explained as "a fractional change in volume as a measure of the increase in randomness" (related to $\frac{dQ}{T}$) How does ...
7
votes
7answers
1k views

Introduction to differential forms in thermodynamics

I've studied differential geometry just enough to be confident with differential forms. Now I want to see application of this formalism in thermodynamics. I'm looking for a small reference, to learn ...
2
votes
1answer
209 views

How to express the heat capacity in terms of heat?

The first law of thermodynamics divides the internal energy change into contributions of heat and work. $$\text dU=\omega_Q-\omega_W,$$ Here I chose the notation to emphasise that the two parts are ...
11
votes
4answers
354 views

Discontinuities and nondifferentiability in thermodynamics

In physics and engineering sources, calculus-based formalisms - whether differential forms on a manifold, or "differentials" of functions of several variables - are presented as a way of modeling and ...