4
votes
2answers
153 views

What information is lost in the symmetrization necessary to derive the BBGKY hierarchy?

The book on Kinetic theory I'm reading derives the BBGKY hierarchy after introducing the reduced distribution functions $f_s(q^1,p_1,q^2,p_2,\dots,q^s,p_s):=\int\ \rho\ \ \mathrm d q^{s+1} \mathrm d ...
2
votes
2answers
85 views

What is the derivation for the exponential energy relation and where does it apply?

Very often when people state a relaxation time $\tau_\text{kin-kin}, \tau_\text{rot-kin}$,, etc. they think of a context where the energy relaxation goes as $\propto\text e^{-t/\tau}$. Related is an ...
12
votes
3answers
326 views

Chemical reaction as state transition?

When considering diffusion of chemicals, the reaction part is business of chemical kinetics, where the relevant characteristics of different substances come from collision theory together with some ...