4
votes
1answer
98 views

Does the Kelvin have a rigorous definition?

From Wikipedia: The kelvin is defined as the fraction 1⁄273.16 of the thermodynamic temperature of the triple point of water. That presupposes that we can take a fraction of temperature. Now, ...
1
vote
1answer
347 views

Which one true in First law of thermodynamics: $Q = \Delta U \pm W = \Delta U \pm p\Delta V$ or $\Delta U= \Delta Q + \Delta W $?

Which one true in First law of thermodynamics: $Q = \Delta U \pm W = \Delta U \pm p\Delta V$? (where $\Delta U$ is change of internal energy, $W$ work made by system and $Q=cm\Delta T $ heat made ...
4
votes
3answers
436 views

Is temperature an extensive property, like density?

I was thinking about it some time ago, and now that I've discovered this site I would like to ask it here because I couldn't work it out then. I know that the higher temperature the air in my room ...
2
votes
1answer
87 views

nature of glass transition

I am reading in some book: "The glass transition is similar in appearance to a second-order phase transition, but it is not a true thermodynamic phase transition. This is because the transition ...
0
votes
1answer
277 views

Energy versus free-energy diagram

Energy versus free energy diagram. I haven't been able to find an adequate definition of these two terms in relation to each other. Could someone point me in the right direction, please? From Borrell ...
5
votes
3answers
444 views

Can temperature be defined as propensity to transmit thermal energy?

I was recently surprised to learn that defining temperature isn't easy. For a long time, it was defined operationally: how much does a thermometer expand. Also surprising, temperature isn't a ...