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1answer
135 views

Reciprocal Lattice of a non-bravais lattice

Is a reciprocal lattice defined for non-Bravais lattices? I'm trying to work out one for HCP structure and not figuring it out.
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1answer
84 views

Why can't a dislocation terminate in the bulk?

We are told that they can only terminate on surfaces, grain boundaries or other dislocations but we are not told why they can't terminate inside the crystal.
2
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1answer
155 views

What does (001) Silicon mean?

If someone gives me a thin film of Si, and they tell me it's (001) Si, does that mean that the (001) planes of Si are the ones making up the surface of the film?
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0answers
49 views

How can I get the lattice constant of a salt?

This is probably a very dummy question, but I am not able to solve it on my own. Given that the radius of $Li^+$ ions is 76 picometers, and the radius of $F^-$ is 133 pm, I would expect the size of a ...
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0answers
34 views

Transmissivity of Liquid Crystals in the near-infrared range

The gist of my query is in the title. I have been searching for papers and studies that could provide transmission curves (in nematic liquid crystals) across the visible to near-IR range (or from ...
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1answer
62 views

Translation invariance in crystals

Context: solid state physics - dynamics of atoms in crystals. Coupling constants are defined as: \begin{align*} \frac{\partial^2\Phi}{\partial r_{nai}\partial r_{mbj}} = \Phi_{nai}^{mbj} ...
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1answer
198 views

Ashcroft Mermin Solid State Eq. 22.15

I recently read a paper on Specific heat of a Classical Crystal: Dulong-Petit law. In Eq. 22.15, I don't understand why the ionic displacement $\mathbf{u}$ and ...
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2answers
53 views

Conductivity of a crystalline solid

In a crystalline solid each atomic level 'splits' into n levels (n = number of atoms in the system). When the number of atoms is large each level becomes replaced by a band of closely spaced levels. ...
3
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1answer
162 views

Difference in chemical potential in supersaturated solutions

I have been more or less struggeling to understand an equation that is apparently used in almost all books covering crystals in any way. Basically every book that I have found explains the following: ...
2
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1answer
89 views

Experimental Evidence of Random Tiling Limit Shapes

In the area of random tilings, there are many results that fall under the term "Arctic Circle Theorems." This roughly means that if one chooses a tiling of a specific region uniformly at random, then ...
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0answers
20 views

How to derive the exponential distribution for the Pool-Frenkel effect?

For the Pool-Frenkel effect, the external electrical field $E_{ext}$ reduces barrier by a potential energy amount $U_{ext}(r_{m})$, where $r_{m}$ is the distance maximizing the total potential enrgy ...
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0answers
48 views

Diffusion coefficient of a crystal

I've been trying to work this out so I can give a hand waving argument for one of the effects I'm observing on the fly and I find myself going down a rabbit hole that seems way too complicated for ...
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0answers
52 views

How does a liquid crystal on Silicon affect the phase of incident light?

When a polarized light beam is directed to a phase-only LCoS system how is the phase modulated ? What is the physical effect behind ? Does voltage modulation has an impact on birefringence ?
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0answers
163 views

Bragg's law in photonic crystals

So in photonic crystals when looking at diffraction the refraction of light has to be taken into account. I am told this would lead to the "photonic bragg's law" which is $$n \lambda = ...
0
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1answer
282 views

Overview and doubts about Bloch's theorem and the concept of partial density of states

So I have a large confusion with QM as applied to solid state. The following is a summary of what I know, what I think I know, and what I know I don't know. I hope to stir a discussion that will help ...
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2answers
173 views

How strong is electron degeneracy pressure?

I'm trying to get some specific numbers for electron degeneracy that I can understand, using a concrete example. Take for example this portion of carbon crystal: Exactly how much energy would be ...
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0answers
36 views

Type-II SHG of linearly polarized light

It's possible to perform type-II frequency doubling of unpolarized light in suitable nonlinear crystals. But for a single beam of linearly polarized input light, is it still possible to do type-II ...
4
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0answers
30 views

What groups of symmetry are most suited for filling uniformely a spherical 3D space, whilst possessing the lowest possible surface-to-volume ratio?

I am looking for the closest known approximate solution to Kelvin foams problem that would obey a spherical symmetry. One alternative way of formulating it: I am looking for an equivalent of ...
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0answers
17 views

Impurities involved in nucleation centres

When magmas begin to crystallise, a first step is the formation of a crystal nucleus around an impurity (nucleation centre), whereby a few of the right atoms get together to form a speck of a crystal. ...
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0answers
74 views

Bragg's law - intensity “sensitivity” to lattice spacing or scattering angle

I don't understand this sentence (emphasis added): A consideration of Bragg's law (nλ = 2dsinθ), i.e. the relationship between scattering angle (θ) and the interplanar spacing (d) shows that if ...
4
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1answer
117 views

Topological Insulators: is HgX a special case?

I got confused by reading this article: Francois Virot, Roland Hayn, Manuel Richter, and Jeroen van den Brink. “Engineering topological surface-states: HgS, HgSe and HgTe.” arXiv preprint ...
0
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1answer
42 views

How does a vacancy become mobile during annealing?

The Nitrogen Vacancy (NV) centre is a defect in diamond consisting of a substitutional nitrogen atom accompanied by a vacant nearest-neighbour lattice site. Substitutional nitrogen impurities are ...
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3answers
340 views

Are synthetically-produced diamonds as hard as natural diamonds?

I was having a discussion with my friend about the intrinsic worthlessness of diamonds (DeBeers and whatnot) and how synthetic diamonds haven't caught on, again because of the marketing/propoganda ...
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2answers
145 views

Simplest derivation of Fourier transform for periodic functions (in crystal lattice)?

What is the simplest derivation of the following two well-known formulas that work for crystal lattice [1]: $$ F[f(\mathbf{x})] \equiv \tilde f(\mathbf{G}) = {1\over\Omega_\mathrm{cell}} ...
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2answers
169 views

How to derive inverse Fourier transform for periodic functions (in crystal lattice)?

I would like to derive the following two well-known formulas that work for crystal lattice [1]: $$ F[f(\mathbf{x})] \equiv \tilde f(\mathbf{G}) = {1\over\Omega_\mathrm{cell}} ...
2
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2answers
344 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
0
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1answer
658 views

Interpretation Born-Von Karman boundary conditions

The cyclic Born-Von Karman boundary condition says that if we consider a one dimensional lattice with length $L$, and if $\psi(x,t)$ is the wavefunction of an electron in this lattice, then we can say ...
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0answers
181 views

Interpreting a Hamiltonian in terms of 'hopping' operators

I am having some trouble interpreting a Hamiltonian in terms of "hopping" operators. The Huckel model for nearest neighbour interaction in graphene is given by $$H=-t\sum_\vec{R}|\vec ...
0
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1answer
117 views

Dispersion relation of silicon

In the case of dispersion relation of silicon having crystal plane orientation 111; what is the Sellmeier's equation for refractive index $n$ of silicon orientation 111 & what it's extinction ...
2
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0answers
116 views

Lattice theory in mathematics and physics

I have undertaken a project examining lattice model and trying to construct algorithm that could work on all lattice (in physical sense, or crystal structure). I notice there is a branch in ...
4
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1answer
195 views

Anisotropic refractive index with isotropic components?

In relation to my question here I wanted to make sure that my physical argument was not flawed. Anisotropic properties, (especially refractive index) is characteristic of a well-ordered solid ...
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0answers
152 views

Bloch's theorem and Bloch's state

The question is not so much about the theorem, but more about what it means in this context: see this link. So yes, because of Bloch's theorem the Hamiltonian eigenstates in a crystalline system can ...
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0answers
58 views

What is the physical meaning of group velocity for elastic waves through crystals?

In a chapter about phonons they define group speeds for elastic waves in crystals as the derivative of the dispersion relation: $$v_g = \frac{d{\omega}}{d{k}} $$ I wonder though how they come to ...
0
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1answer
24 views

What are degenerate transversal oscillation modes?

This is just a question about terminology that is used in the beginning of a chapter about phonons. In a simple cubic crystal, we can consider elastic oscillations in f.i. the [100] direction. In ...
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1answer
208 views

What determines Phonon - Phonon collisions?

I was in Solid State Physics lecture yesterday and we BRIEFLY went over what causes phonons to collide with one another. Things such as crystal imperfections, boundaries, Temperature, but I was ...
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0answers
94 views

Is there a derivation of all possible Bravais lattices in 2D and 3D?

Do any of you know a (possibly elegant) derivation of all possible Bravais Lattice and the Crystallographic Group of Lattices in 2 and 3 dimensions? Group theory /abstract nonsense approaches are ...
0
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1answer
114 views

Plane Wave expansion method

I really don't know if this is the right forum to ask the question...but please help me if you can!! I was going through the Plane Wave Expansion Method Derivation...But to be honest I could not find ...
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4answers
9k views

Why does ice have a lower density than water?

Can someone explain me why is ice lighter than water? As I know, all solids are usually heavier than the liquids (correct me if I am wrong).
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0answers
306 views

How to demonstrate that there are just 14 types of Bravais lattice?

Is it possible to demonstrate that there are just 14 types of Bravais lattice without the knowledge of group theory?
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2answers
476 views

Why do some things crystallize? (And others don't, for that matter.)

Ice, for example, will form a crystal when frozen under certain circumstances. Why is this the case for ice? While on the subject of water crystallization, why do snowflakes usually form in base 6 ...
2
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1answer
313 views

Regarding Bravais lattices

There is 'End-Centered' Orthorhombic lattice . Why this type is not in 'Cubic' lattice ? On which basis did Bravais propose his theory ?
0
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1answer
73 views

Methods for determination of crystal lattice's homogeneity

I know of X-Ray diffraction, which produces a pattern corresponding to the inverse Fourier Transform of the lattice (reciprocal lattice). While this method is widely employed, it provides more ...
3
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4answers
277 views

Molecule vs Crystal

Feynman mentions in his lectures: ...the concept of a molecule of a substance is only approximate and exists only for a certain class of substances. It is clear in the case of water that the ...
1
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3answers
123 views

Should a polyatomic crystal behave similarly to the bulk of each/either of its constituent elements?

Generally, metals are usually fairly conductive, but their oxides aren't. I know conductivity is just one attribute, but in general, should you expect a, say, diatomic bulk crystal's properties to be ...
4
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1answer
149 views

Do indirect optical transitions “cool” the material a little?

So I'm reading in Ashcroft and Mermin about indirect optical transitions: So, a photon comes in, and it only excites the electron across the indirect band gap if a phonon with the appropriate wave ...
2
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0answers
82 views

The boundary between polycrystalline and crystalline

My current understanding of solid crystalline-like materials (please correct me if I'm wrong!) is that it is a continuum in terms of crystallinity, from amorphous (basically no periodicity) to single ...
1
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1answer
414 views

gaussian fitting of xrd peaks

I am reading a paper regarding the nano crystalline material with hexagonal crystal structure. In that paper in order to find out lattice parameter of hexagonal crystal structure they have fitted a ...
2
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1answer
94 views

How to homegrow large, momocrystalline water ice crystals

This is a follow up to this question:Can one get clear ice crystals from a dirty suspension?. How could one grow a large - meaning visible with the naked eye - water ice crstal with common household ...
1
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1answer
145 views

What does the wavevector $\textbf{k}$ mean?

In Ashcroft, Mermin Solid State Physics, Eq. 17.43 is $$ \epsilon(\textbf{k}) = \frac{\hbar^2 k^2}{2m} - e\phi(\textbf{r}) $$ where $\textbf{k}$ is the wavevector and all other symbols have their ...
1
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1answer
51 views

localized electrons in the crystals

Why electrons in low lying levels of individual atoms stay localized in their own atoms in a crystal? Doesn't this contradict Bloch's theorem?