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How many unique crystal faces does a given unit cell have?

I am not sure how to best approach this problem. "A diamond crystal is composed of an enormous number of cubic unit cells that are stacked to produce crystal faces. Stacking of cubes to produce an ...
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1answer
95 views

Crystal structure of Silicon

From what I was reading, Silicon has a FCC unit cell but they also said that the Silicon atoms form a tetrahedron at 109 degrees from each other. Then they said that the tetrahedron is formed by ...
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0answers
23 views

Binding forces in crystalline solids

I am referring to rocks in this instance. Individual crystals grow together in an igneous rock as it solidifies. I know that the SiO4 tetrahedron is the basic building unit of silicate minerals, and ...
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1answer
46 views

Can I tear apart a pipe with magnetostriction? And how big field should I use?

As I know, with magnetostriction we can "stretch" its unit cell. The stronger is the field, the more it expands the cell. Using alternating current in coils that induce magnetic field we can stretch ...
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0answers
34 views

Quantization in a 2D quasicrystal?

let be the Schroedinger equation with a potential in a quascristal $$ -( \partial _{x}^{2}+ \partial _{y}^{2}) \Psi (x,y)+ V(x,y)=E_{n} \Psi (x,y) $$ if we were in a crystal we could impose the ...
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1answer
79 views

How corner atom of a cube is shared by 8 atoms? [closed]

Since each atom is at the corner of a cube and 8 cubes meet at each corner. Therefore each atom is shared by 8 cubes. But I don't visualize it, so please tell how I Visualize it.
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1answer
55 views

Crystal lattices in solid state

I found this problem in Christman's book fundamental of solid state physics What is the Miller index for a plane parallel to both $3\vec{a}+\vec{c}$ and $\vec{b}$, in any lattice?
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2answers
871 views

How many atoms exist within a continuum body?

Materials, such as solids, liquids and gases, are composed of molecules separated by "empty" space. On a microscopic scale, materials have cracks and discontinuities. However, certain physical ...
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1answer
158 views

Does graphene have a honeycomb lattice?

In my grand ignorance I would state that graphene has a honeycomb lattice. Some tend to agree with me and some others do not. I'm curious to know what members of the SE community think is the right ...
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1answer
128 views

Help needed to understand the dispersion curve of a 1D lattice with diatomic basis

I am trying to understand the dispersion curve (as shown below) of a 1D lattice with diatomic basis. Here are my questions: Can both optical and acoustic branch of phonon simultaneously exist in ...
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1answer
30 views

Why Nitrides have internal polarization?

Why GaN has internal polarization? I know that in wurtzite crystal structure, the atomistic bonds are not equivalent and as a result there appears a net dipole and consequently a polarization. But ...
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2answers
97 views

How many are the points which are $n$th nearest to a certain point in a hexagonal lattice

Suppose there are infinite points arranged as hexagonal lattice. The question is the one as the title. First we choose a point called $A$. Then when we count the $n$th nearest points to $A$, what ...
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1answer
101 views

Calculating number of atoms per cell in a crystal. Nonsense question in class

I don't agree at all with this question, and I think my teacher does not understand his topic. I hope you can prove me wrong. The question was this one: Potassium crystallises in a Body Centered ...
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0answers
58 views

Crystallography: relationship between side length and radius of atom

For a FCC the relationship between the radius and the side length 'a' is 4r=(2)^.5 a And this is derived by drawing a diagonal across one of the faces of the unit cell. However, is this meant to be ...
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0answers
46 views

What is the the real world interpretation of the high dimensionality of quasicrystals?

One of the examples of the problems of 5-fold symmetry is that pentagons tiled on a 2D plane do not completely fill that plane, leaving voids. This may be solved by "folding" it into 3D space, and ...
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1answer
147 views

Can you explain why crystals form without thermodynamics?

I know that the basic reason that solid crystals form is because it's the lowest energy configuration (i.e. this). I am looking for an intuitive explanation for this process, one that does not involve ...
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1answer
71 views

Why aren't base-centered orthorhombic Bravais lattice simple monoclinic?

I am learning 7 crystal systems and 32 Bravais lattices. I am quite confused about why a base-centered orthorhombic Bravais lattice is not a simple monoclinic one, if we take two edges and a half ...
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1answer
620 views

$c/a$ ratio for an ideal hexagonal close-packed (HCP) structure [closed]

Show that the $c/a$ ratio for an ideal hexagonal close-packed (HCP) structure is $\left(\frac{8}{3}\right)^\frac{1}{2} = 1.633$. I believe $a$ is the length of $a_1$ and $a_2$. I figured that ...
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0answers
19 views

What are some structures which minimize surface stress upon expansion

Intro I am currently researching into a problem involving the cyclical expansion and contraction of a 3 layered structure comprised of an internal metal encased by another metal encased in an outer ...
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2answers
90 views

Quantity to measure order in crystals

Imagine a cubic lattice for simplicity and put some atomic configuration inside of each unit cell. Lattice is of course a highly ordered entity (long range order). Please, how could I quantitatively ...
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2answers
94 views

What exactly are crystal planes and how do they reflect x-rays?

What exactly are crystal planes and how do they reflect x-rays? Are crystal planes real physical planes or just an abstract concept? What are these planes made of? If they are an abstraction, what ...
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1answer
288 views

Crystal Momentum in a Periodic Potential

I'm working through some basic theory on periodic potentials, and I would appreciate help in understanding the crystal momentum. Suppose we have a Bravais lattice with lattice vectors $\textbf{R}$. ...
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1answer
126 views

Lattice geometry and dispersion relation

Is there a general theorem which gives some information about which influence have the lattice geometry (for example sub-lattice structure, square lattice, honeycomb lattice, lattice symmetries, ...) ...
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1answer
74 views

What physical phenomenon occured in this experiment?

I noticed a strange behavior of my experiment. I have a glass container with a fully saturated solution of CuSO4, which I use to grow CuSO4 crystals, by waiting for the water to evaporate. Recently I ...
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0answers
34 views

Mixed-Alloy materials

Short version: Is it a physical problem (crystal structure/grains/redox/etc.) or just a logistics problem (keeping the solutes from homogenizing, molten/solid/temperature related problems) that keeps ...
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0answers
25 views

3-dimensional quasicrystals

As is well known, quasicrystals (i.e. their diffraction patterns) show patterns which can be deciphered and understood via the use Penrose tilings (and aperiodic tilings of the plane in general). ...
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0answers
123 views

Why is there a 'loophole' in Mermin Wagner for rotations?

I'm just starting out in my mathematics career by looking at some simple stuff on broken symmetries in statistical mechanics. Since 3D is 'hard' it would be very nice to look at 2D toy models of ...
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2answers
234 views

Bloch theorem, Energy, Free electron

I'm trying to learn on my own a bit of solid physics to tackle semiconductors afterwards. I'm struggling with the Energy versus $k$ diagrams for a free electron which shows that for a single value of ...
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1answer
22 views

Effect of crystal growth on its scintillation

How does crystal growth affect its scintillation properties? What are possible ways in which growth of CaWO crystals grown via Chochralski method could be modified to avoid non-linearity in its ...
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4answers
328 views

How many of the 230 crystallographic groups are realized in nature?

All of them or only a subset? This is a famous and fundamental result in solid state physics.
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3answers
64 views

How to calculate the density of a polycrystalline sample?

I'm trying to figure out the density (g/cm^3) of La2CuO4. I know that the mass is 405.355 g/mol; what do I have to do to calculate the volume? Thanks!
3
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1answer
33 views

Why do we still get sharp scattering spots with quasi-crystal?

In a quasi-crystal, there is no translational invariance. This means there is no delta-function in the Fourier transform. But to get a sharp scattering spot, we need a delta function. Physically, ...
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2answers
184 views

Bragg diffraction and lattice planes

Crystalline substances show, for certain sharply defined wavelength and incident directions, very sharp peaks of scattered X-ray radiation. From the illustration below we see that we get constructive ...
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1answer
72 views

What is the symmetry difference between simple-cube and body-centered-cube structures

If the lattice types are categorized according to the point group symmetries, then what is the difference, for example, between sc and bcc structures?
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3answers
172 views

Are there materials that get softer with temperature decrease?

Could be there material that begins melting/softening when it's temperature is lowered? I would say no, but I've seen enough physics to know that not always life is so easy. Moreover I think I've ...
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1answer
176 views

Kronig-Penney model

I am studying the Kronig-Penney model as treated in the book by Kittel: Introduction to Solid State Physics. In this model one considers a period potential which is zero in the region $[0,a]$ ...
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2answers
345 views

Bloch's theorem

I am studying Bloch's theorem, which can be stated as follows: The eigenfunctions of the wave equation for a period potential are the product of a plane wave $e^{ik \cdot r}$ times a modulation ...
2
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1answer
100 views

Why does a halocline form?

I was doing an experiment over the last couple of days to try to crystallize alum using a thermal gradient. The idea was that solute at the bottom of my container would be dissolved at a higher ...
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2answers
860 views

Why a mono-atomic crystal layer (2D) can't be stable?

According to Peierls and Landau, 2D crystals were thermodynamically unstable. They can't exist! Of course, this theory was disapproved in 2004 (example: graphene). What is the general definition of ...
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0answers
153 views

Pseudocubic unit cells: how to construct one?

I keep coming across the term pseudocubic unit cell while reading about orthorhombic perovskite structures. No clear explanation ...
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1answer
72 views

How can one reasonably theoretically model polycrystalline materials?

Many techniques are taught in advanced solid state courses but they are almost all derived for perfectly crystalline materials. For example, band structure really only appears theoretically when you ...
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1answer
263 views

Reciprocal Lattice of a non-bravais lattice

Is a reciprocal lattice defined for non-Bravais lattices? I'm trying to work out one for HCP structure and not figuring it out.
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1answer
99 views

Why can't a dislocation terminate in the bulk?

We are told that they can only terminate on surfaces, grain boundaries or other dislocations but we are not told why they can't terminate inside the crystal.
2
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1answer
287 views

What does (001) Silicon mean?

If someone gives me a thin film of Si, and they tell me it's (001) Si, does that mean that the (001) planes of Si are the ones making up the surface of the film?
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1answer
73 views

Translation invariance in crystals

Context: solid state physics - dynamics of atoms in crystals. Coupling constants are defined as: \begin{align*} \frac{\partial^2\Phi}{\partial r_{nai}\partial r_{mbj}} = \Phi_{nai}^{mbj} ...
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1answer
222 views

Ashcroft Mermin Solid State Eq. 22.15

I recently read a paper on Specific heat of a Classical Crystal: Dulong-Petit law. In Eq. 22.15, I don't understand why the ionic displacement $\mathbf{u}$ and ...
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2answers
65 views

Conductivity of a crystalline solid

In a crystalline solid each atomic level 'splits' into n levels (n = number of atoms in the system). When the number of atoms is large each level becomes replaced by a band of closely spaced levels. ...
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1answer
222 views

Difference in chemical potential in supersaturated solutions

I have been more or less struggeling to understand an equation that is apparently used in almost all books covering crystals in any way. Basically every book that I have found explains the following: ...
2
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1answer
108 views

Experimental Evidence of Random Tiling Limit Shapes

In the area of random tilings, there are many results that fall under the term "Arctic Circle Theorems." This roughly means that if one chooses a tiling of a specific region uniformly at random, then ...
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1answer
139 views

Point group symmetries and unit cell

I was wondering if the unit cell (of a given lattice) had to have every point group symmetries of the lattice it defines ? I guess there is no unique way to define a unit cell and that it may not have ...