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6
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1answer
52 views

Is there a tool to measure the chemical potential of a system?

Let's suppose I put you inside a room filled with a gas. You can measure its pressure directly with a barometer. You can measure its temperature directly with a thermometer. Can you measure its ...
1
vote
0answers
28 views

Extra 5/2 tau term in chemical potential of a monoatomic ideal gas? [closed]

The chemical potential of an ideal monoatomic gas should be: $\mu = \tau ln \frac {n}{n_Q}$ http://web.mit.edu/ndhillon/www/Teaching/Physics/bookse5.html I get this result if I derive it using the ...
0
votes
1answer
23 views

why is the chemical potential included in the hamiltonian for a systeme coupeled to a particle reservoir

I am beginning with second quantification language so i saw that if we are in grand canonical ensemble then: $$ H=H_0 - \mu N $$ naturally i thought that this $ \mu $ would be included in the ...
6
votes
2answers
113 views

Why is chemical potential, μ=0 when calculating critical temperature of BECs?

How do we justify taking the chemical potential, $\mu$ as $0$ when calculating the critical temperature of Bose-Einstein Condensates (BECs)? I apologise as I do not how to use LaTeX, for if I did the ...
1
vote
1answer
47 views

Sign conventions in Hubbard model

The Hubbard model is often expressed as $$H=-J\sum\limits_{<i,j>} \sum_\sigma c_{i,\sigma}^{\dagger}c_{j,\sigma} +h.c.+U\sum\limits_{i} c_{i,\uparrow}^{\dagger} c_{i,\downarrow}^{\dagger} ...
5
votes
2answers
135 views

Physic explanation to osmosis

I want to understand the forces involved in osmosis. If I have a molecule of water and one of a salt in the left side of a semi-permeable membrane, and a water molecule at the right side, what forces ...
2
votes
1answer
52 views

Is kinetic energy related to chemical potential?

I wonder if the kinetic energy written as $\frac{d\mathbf x}{dt}\cdot d\mathbf p$ is related to chemical potential? I ask because if I use $\mathbf p = m \frac{d\mathbf x}{dt}$ as a constitutive ...
0
votes
1answer
224 views

Fermi Level: chemical potential vs. electrochemical potential

In solid-state physics it is understood that the Fermi-Level is the electrochemical potential. The Fermi-Level is defined to: However, in thermodynamics this formula is referred to as the ...
2
votes
1answer
75 views

Under what conditions is air is in chemical equilibrium?

I am considering the flow field around a hypersonic glide vehicle at $M=7$. As I understand it, air is in chemical equilibrium if the fluid time scale $t_f \ll t_c$, where $t_c$ is the chemical time ...
2
votes
1answer
109 views

How to compute this change of Gibbs energy for a Van der Waals gas?

The change of Gibbs energy at constant temperature and species numbers, $\Delta G$, is given by an integral $\int_{p_1}^{p_2}V\,{\mathrm d}p$. For the ideal gas law $$p\,V=n\,RT,$$ this comes down to ...
1
vote
1answer
46 views

What's the difference between the Fermi level and the electrochemical potential?

I was asked in a Thermostatistics test to compute the electrochemical potential $\mu(T)$ and the Fermi level $\epsilon_F$ for a system of non-interacting fermions, with two possible energetic states ...
3
votes
1answer
132 views

What does chemical potential $\mu = 0$ mean?

First off, just to be clear, the chemical potential being equal to zero is different from not having a chemical potential at all (e.g. a photon gas)? Now: physically, what does having chemical ...
0
votes
0answers
14 views

how to show that the chemical potential goes with O(1/V)?

In statistical mechanics books $\mu=O\left(\frac{1}{V}\right)$ is being used to show the nature of the chemical potential when $T\to0$ Unfortunately, I was not able to figure out how to see how this ...
2
votes
1answer
80 views

Understanding chemical potential in AdS/CFT

I always find it very difficult to understand the notion of chemical potential physically/intuitively unlike pressure and temperature in statistical mechanics. Can some one suggest some nice ...
0
votes
1answer
112 views

Work and chemical energy “paradox”

This is a mistake I've seen many people make, a few physicists included, but I haven't ever seen a satisfactory explanation for what's going on. Apologies for the lengthy setup. Setup Suppose I ...
1
vote
0answers
32 views

Chemical Potential at Triple Point [closed]

How does one calculate the chemical potential/Gibbs Free energy at the triple point of a substance given only the temperature and pressure of the triple point, and the volume of each phase? I cannot ...
5
votes
2answers
85 views

Why $\epsilon > \mu$ for Bose-Einstein distribution (but not for Fermi-Dirac)?

For fermions $$\bar{n}_{FD}=\frac{1}{e^{(\epsilon -\mu)/kT}+1}$$ and $\epsilon$ can be bigger or small than $\mu$. However, for bosons: $$\bar{n}_{BE}=\frac{1}{e^{(\epsilon -\mu)/kT}-1}$$ which ...
1
vote
0answers
106 views

Diffusion of a chemical proof (fick's law general) [closed]

I want to prove that: $$C(x,t)= \frac{C_0}{\sqrt{4\pi Dt}} \exp\left[{\frac{-x^{2}}{4Dt}}\right]$$ I've proven so far that Fick's law coupled with the conservation of mass (assuming no influx or ...
0
votes
0answers
18 views

Effect of applying a gate voltage to a strongly correlated system

In strongly correlated systems, there are different ways of driving a metal-insulator transition (MIT), say, bandwidth control, filling control and dimensionality control (See MIT). As for the method ...
0
votes
1answer
69 views

How to thermodynamically understand process of burning a piece of coal?

Let's imagine that I have a match in hand and nugget of coal on my desk. Then I light up the match and place it for few seconds near the coal so a tiny piece of nugget catches fire. Then another piece ...
2
votes
0answers
186 views

Confusing Chemical potential of mixtures

I feel that there are very few textbook that treat the chemical potential of mixtures in an understandable clear way, which is why I wanted to ask here about certain things? Although I do not have a ...
3
votes
1answer
133 views

Chemical Potential, Boltzmann

The electrochemical potential of an ion i in an electrolytic solvent is given by: \begin{align}\mu_i(\vec r) &= \mu_i^0 + RT \ln(a_i(\vec r))\\& = \mu_i^0 + RT \ln(\gamma_i(\vec r) c_i(\vec ...
1
vote
3answers
594 views

If we connect a long wire to a battery, will battery produce more electrons?

I actually have three related questions: An open circuit chemical cell separates charges creating a surplus of electrons on its negative terminus and a shortage of electrons on its positive terminus. ...
2
votes
0answers
250 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
1
vote
1answer
54 views

Equivalence of different definitions for chemical potential

In some books, the chemical potential is defined in term of the Gibbs energy as $$ \mu_i \equiv \left( \frac{\partial G}{\partial n_i} \right)_{P,T,n_j} $$ where $n_j$ indicates all mole numbers ...
2
votes
2answers
69 views

Energy Flux due to Diffusion

Per the Fundamental Thermodynamic Relation, I know that the chemical potential of $i$ represents the energy which would added to a system if a particle of $i$ were added with all other system ...
2
votes
1answer
123 views

Ambiguity on the notion of potential in electrical circuits?

As everybody else I have been taught elementary electrical circuits from secondary school to engineering level in analog electronics at university. Invariably, the notion of potential used to ...
1
vote
1answer
83 views

Chemical potentials for multicomponent solids

I have a problem understanding how to deal with the chemical potential when two thermodynamic systems are in contact. For simplicity, let us consider $T=0\ K$. We have a system that is composed of two ...
1
vote
2answers
110 views

If batteries are a source of energy, would not lower-valued resistors cause a violation of the conservation of energy?

Here's the conundrum I have been facing. Yesterday I asked the question: how can batteries constantly motivate electrons to complete a circuit? (What maintains constant voltage in a battery?) After ...
4
votes
1answer
639 views

What maintains constant voltage in a battery?

I know there's lots of questions that address similar situations, (Batteries connected in Parallel, Batteries and fields?, Naive Question About Batteries, and the oft-viewed I don't understand ...
7
votes
1answer
151 views

Role of the canonical ensemble and electric charge in AdS/CFT

If we consider a charged black hole in AdS spacetime, we can either do thermodynamics in the grand canonical or the canonical ensemble. In the former, we fix the electrostatic potential ...
0
votes
0answers
79 views

Proving $RTln(a_i)$ equal to non PV work done by system,where $a_i$ is activity

First of all many here will might say that it is Chemistry question.If you think so then read this article and then answer question. Question is --- We know chemical potential is defined as $\mu_i ...
0
votes
1answer
982 views

Chemical potential of Bose-Einstein condensation

This is a problem in An Introduction to Thermal Physics. (a)(b) is easy to work out. In (c), I use the formula $N_{excited}=(\frac{T}{T_c})^{3/2}N, \ (T<T_c)$ to calculate how many atoms are ...
4
votes
1answer
275 views

Difference in chemical potential in supersaturated solutions

I have been more or less struggeling to understand an equation that is apparently used in almost all books covering crystals in any way. Basically every book that I have found explains the following: ...
1
vote
1answer
203 views

Questions about Statistical Mechanics

For grand partition ensemble, is it true that the introduction of chemical potential allows us to have the sum of number of the particles in each state to be the total number of particles ("On ...
4
votes
4answers
5k views

Meaning of the chemical potential for a boson gas

My lecturer told me that the mu is the Chemical potential is zero or negative, in the following example, mathematically it acts as a Normalisation constant. But is there any Physical insight about why ...
2
votes
1answer
233 views

Does non-conservation of number of particles imply zero chemical potential?

In the systems like photon gas in a cavity and phonon gas in a solid number of particles is not conserved and chamical potential is zero. Is this a general rule? If yes, how zero chemical potential is ...
3
votes
1answer
260 views

Vortices and chemical potential in topological superconductors

I am trying to read up some review articles about Majorana physics in topological material, but I am not really familiar with the condensed matter terminology (with condensed matter in general I ...
3
votes
1answer
1k views

Diffusion of gas in a liquid with changing pressure and solubility (chemical potential)

Modelling the diffusion of a gas dissolved in water in a vertical column of water, several meters deep. Also assuming the water is completely still, so only diffusion plays a role. (Actually a model ...
2
votes
1answer
269 views

Mathematical form of chemical potential difference and entropy production

I'm trying to understand the form of the 'force' which drives chemical reactions, ie. the difference in chemical potential, also sometimes called the 'affinity'. $$\Delta \mu = - kT ln ...
9
votes
2answers
1k views

Could the chemical potential of a Bose gas be zero?

Could the chemical potential of a Bose gas be zero ? If it was the case, we will have an infinite number of particles in the ground state ! No ? But I've heard that for $T < T_c$, $\mu = 0$, so I ...
5
votes
4answers
2k views

Chemical potential of a Bose gas

In my course, there is this fact : In a Bose gas, the chemical potential $\mu$ must always be lower than the smaller level of energy $\epsilon_0$. I find this strange, because if we put a Bose ...
7
votes
2answers
470 views

How much Bicarbonate of Soda and Vinegar would I need to reach space?

So here is my problem - as part of my job I present some science demonstrations to children and one of the tricks I regularly use is the bicarb/acetic acid rocket. I thought the other day that a ...
2
votes
2answers
111 views

Ashcroft Mermin Eq. 17.47ff

In "Solid State Physics" by said authors, Eq. 17.46 is $$ \rho^{ind}(\textbf{r}) = - e[n_0(\mu + e\phi(\textbf{r})) - n_0(\mu)]$$ and then the authors write In the present case we assume that ...
0
votes
1answer
214 views

Ways to experimentally control the chemical potential of a solid state system

When working in the grand canonical ensemble we write the grand potential as $\Omega = \Omega (T,V,\mu)$. In this case we are taking the chemical potential $\mu$ to be an independent variable. This ...
3
votes
1answer
434 views

Why do hydrogen atoms attract?

That is, why is the potential energy with the orbitals overlapping less than with the Hydrogen atoms 'independent'. Similarly, why is a noble gas configuration stabler than if an electron were to be ...
9
votes
3answers
349 views

Is particle number a problem for formulating statistical physics in a mathematically rigorous manner?

Quantities like the chemical potential can be expressed as something like $$\mu=-T\left(\tfrac{\partial S}{\partial N}\right)_{E,V}.$$ Now the entropy is the log some volume, which depends on the ...
1
vote
2answers
2k views

What is the physical or mathematical meaning of the Gibbs-Duhem equation?

The Gibbs-Duhem equation states $$0~=~SdT-VdP+\sum(N_i d\mu_i),$$ where $\mu$ is the chemical potential. Does it have any mathematical (about intensive parameters) or physical meaning?
3
votes
1answer
1k views

What does activation energy actually do?

Spontaneous (exothermic) chemical reactions often require a push from the addition of externally supplied energy. This energy is often called activation energy. What does activation energy actually ...
4
votes
1answer
882 views

Energy per particle vs. chemical potential vs. evaporation energy

There is a system of N particles. They interact and are bound together with a binding energy Eb (or potential energy). To characterize the system there are multiple terms Energy per particle Eb(N)/N ...