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1answer
64 views

Work and chemical energy “paradox”

This is a mistake I've seen many people make, a few physicists included, but I haven't ever seen a satisfactory explanation for what's going on. Apologies for the lengthy setup. Setup Suppose I ...
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0answers
26 views

Chemical Potential at Triple Point [closed]

How does one calculate the chemical potential/Gibbs Free energy at the triple point of a substance given only the temperature and pressure of the triple point, and the volume of each phase? I cannot ...
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2answers
65 views

Why $\epsilon > \mu$ for Bose-Einstein distribution (but not for Fermi-Dirac)?

For fermions $$\bar{n}_{FD}=\frac{1}{e^{(\epsilon -\mu)/kT}+1}$$ and $\epsilon$ can be bigger or small than $\mu$. However, for bosons: $$\bar{n}_{BE}=\frac{1}{e^{(\epsilon -\mu)/kT}-1}$$ which ...
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0answers
37 views

Diffusion of a chemical proof (fick's law general) [closed]

I want to prove that: $$C(x,t)= \frac{C_0}{\sqrt{4\pi Dt}} \exp\left[{\frac{-x^{2}}{4Dt}}\right]$$ I've proven so far that Fick's law coupled with the conservation of mass (assuming no influx or ...
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0answers
15 views

Effect of applying a gate voltage to a strongly correlated system

In strongly correlated systems, there are different ways of driving a metal-insulator transition (MIT), say, bandwidth control, filling control and dimensionality control (See MIT). As for the method ...
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1answer
42 views

How to thermodynamically understand process of burning a piece of coal?

Let's imagine that I have a match in hand and nugget of coal on my desk. Then I light up the match and place it for few seconds near the coal so a tiny piece of nugget catches fire. Then another piece ...
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0answers
172 views

Confusing Chemical potential of mixtures

I feel that there are very few textbook that treat the chemical potential of mixtures in an understandable clear way, which is why I wanted to ask here about certain things? Although I do not have a ...
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1answer
81 views

Chemical Potential, Boltzmann

The electrochemical potential of an ion i in an electrolytic solvent is given by: \begin{align}\mu_i(\vec r) &= \mu_i^0 + RT \ln(a_i(\vec r))\\& = \mu_i^0 + RT \ln(\gamma_i(\vec r) c_i(\vec ...
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3answers
217 views

If we connect a long wire to a battery, will battery produce more electrons?

I actually have three related questions: An open circuit chemical cell separates charges creating a surplus of electrons on its negative terminus and a shortage of electrons on its positive terminus. ...
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0answers
31 views

Chemical potential and origin of pressure in a solid

Pressure of a gas is related to the rate of change of momentum of the particles; the temperature is the mean kinetic energy of the particles. Can the chemical potential be given a similar physical ...
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0answers
100 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
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1answer
46 views

Equivalence of different definitions for chemical potential

In some books, the chemical potential is defined in term of the Gibbs energy as $$ \mu_i \equiv \left( \frac{\partial G}{\partial n_i} \right)_{P,T,n_j} $$ where $n_j$ indicates all mole numbers ...
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2answers
45 views

Energy Flux due to Diffusion

Per the Fundamental Thermodynamic Relation, I know that the chemical potential of $i$ represents the energy which would added to a system if a particle of $i$ were added with all other system ...
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0answers
32 views

What's the difference between electrostatic potential and electrochemical potential along a (semi)conductor?

According to wikipedia: the electrochemical potential, $\bar{\mu}$, sometimes abbreviated to ECP, is a thermodynamic measure of chemical potential that does not omit the energy contribution of ...
2
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1answer
94 views

Ambiguity on the notion of potential in electrical circuits?

As everybody else I have been taught elementary electrical circuits from secondary school to engineering level in analog electronics at university. Invariably, the notion of potential used to ...
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1answer
67 views

Chemical potentials for multicomponent solids

I have a problem understanding how to deal with the chemical potential when two thermodynamic systems are in contact. For simplicity, let us consider $T=0\ K$. We have a system that is composed of two ...
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2answers
72 views

If batteries are a source of energy, would not lower-valued resistors cause a violation of the conservation of energy?

Here's the conundrum I have been facing. Yesterday I asked the question: how can batteries constantly motivate electrons to complete a circuit? (What maintains constant voltage in a battery?) After ...
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1answer
214 views

What maintains constant voltage in a battery?

I know there's lots of questions that address similar situations, (Batteries connected in Parallel, Batteries and fields?, Naive Question About Batteries, and the oft-viewed I don't understand ...
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1answer
102 views

Role of the canonical ensemble and electric charge in AdS/CFT

If we consider a charged black hole in AdS spacetime, we can either do thermodynamics in the grand canonical or the canonical ensemble. In the former, we fix the electrostatic potential ...
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0answers
61 views

Proving $RTln(a_i)$ equal to non PV work done by system,where $a_i$ is activity

First of all many here will might say that it is Chemistry question.If you think so then read this article and then answer question. Question is --- We know chemical potential is defined as $\mu_i ...
0
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1answer
568 views

Chemical potential of Bose-Einstein condensation

This is a problem in An Introduction to Thermal Physics. (a)(b) is easy to work out. In (c), I use the formula $N_{excited}=(\frac{T}{T_c})^{3/2}N, \ (T<T_c)$ to calculate how many atoms are ...
3
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1answer
209 views

Difference in chemical potential in supersaturated solutions

I have been more or less struggeling to understand an equation that is apparently used in almost all books covering crystals in any way. Basically every book that I have found explains the following: ...
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1answer
176 views

Questions about Statistical Mechanics

For grand partition ensemble, is it true that the introduction of chemical potential allows us to have the sum of number of the particles in each state to be the total number of particles ("On ...
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3answers
2k views

Meaning of the chemical potential for a boson gas

My lecturer told me that the mu is the Chemical potential is zero or negative, in the following example, mathematically it acts as a Normalisation constant. But is there any Physical insight about why ...
2
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1answer
168 views

Does non-conservation of number of particles imply zero chemical potential?

In the systems like photon gas in a cavity and phonon gas in a solid number of particles is not conserved and chamical potential is zero. Is this a general rule? If yes, how zero chemical potential is ...
3
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1answer
199 views

Vortices and chemical potential in topological superconductors

I am trying to read up some review articles about Majorana physics in topological material, but I am not really familiar with the condensed matter terminology (with condensed matter in general I ...
3
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1answer
1k views

Diffusion of gas in a liquid with changing pressure and solubility (chemical potential)

Modelling the diffusion of a gas dissolved in water in a vertical column of water, several meters deep. Also assuming the water is completely still, so only diffusion plays a role. (Actually a model ...
2
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1answer
201 views

Mathematical form of chemical potential difference and entropy production

I'm trying to understand the form of the 'force' which drives chemical reactions, ie. the difference in chemical potential, also sometimes called the 'affinity'. $$\Delta \mu = - kT ln ...
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2answers
777 views

Could the chemical potential of a Bose gas be zero?

Could the chemical potential of a Bose gas be zero ? If it was the case, we will have an infinite number of particles in the ground state ! No ? But I've heard that for $T < T_c$, $\mu = 0$, so I ...
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4answers
1k views

Chemical potential of a Bose gas

In my course, there is this fact : In a Bose gas, the chemical potential $\mu$ must always be lower than the smaller level of energy $\epsilon_0$. I find this strange, because if we put a Bose ...
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2answers
427 views

How much Bicarbonate of Soda and Vinegar would I need to reach space?

So here is my problem - as part of my job I present some science demonstrations to children and one of the tricks I regularly use is the bicarb/acetic acid rocket. I thought the other day that a ...
2
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2answers
109 views

Ashcroft Mermin Eq. 17.47ff

In "Solid State Physics" by said authors, Eq. 17.46 is $$ \rho^{ind}(\textbf{r}) = - e[n_0(\mu + e\phi(\textbf{r})) - n_0(\mu)]$$ and then the authors write In the present case we assume that ...
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1answer
199 views

Ways to experimentally control the chemical potential of a solid state system

When working in the grand canonical ensemble we write the grand potential as $\Omega = \Omega (T,V,\mu)$. In this case we are taking the chemical potential $\mu$ to be an independent variable. This ...
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1answer
326 views

Why do hydrogen atoms attract?

That is, why is the potential energy with the orbitals overlapping less than with the Hydrogen atoms 'independent'. Similarly, why is a noble gas configuration stabler than if an electron were to be ...
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3answers
328 views

Is particle number a problem for formulating statistical physics in a mathematically rigorous manner?

Quantities like the chemical potential can be expressed as something like $$\mu=-T\left(\tfrac{\partial S}{\partial N}\right)_{E,V}.$$ Now the entropy is the log some volume, which depends on the ...
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2answers
1k views

What is the physical or mathematical meaning of the Gibbs-Duhem equation?

The Gibbs-Duhem equation states $$0~=~SdT-VdP+\sum(N_i d\mu_i),$$ where $\mu$ is the chemical potential. Does it have any mathematical (about intensive parameters) or physical meaning?
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1answer
1k views

What does activation energy actually do?

Spontaneous (exothermic) chemical reactions often require a push from the addition of externally supplied energy. This energy is often called activation energy. What does activation energy actually ...
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1answer
782 views

Energy per particle vs. chemical potential vs. evaporation energy

There is a system of N particles. They interact and are bound together with a binding energy Eb (or potential energy). To characterize the system there are multiple terms Energy per particle Eb(N)/N ...
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5answers
8k views

How does evaporation affect the temperature of the air?

A wet object or a volume of water will decrease in temperature due to the effect of evaporation. We understand this to be because of the molecular kinetics, where the faster water molecules escape ...
2
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1answer
338 views

How does the internuclear repulsion vary in Hydrogenic atom collision?

Hydrogen fusion requires two hydrogen nuclei to get close enough (typically a few fm) to fuse. Much of the problem of creating a fusion reactor is overcoming the Coulomb repulsion between a pair of ...
4
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1answer
295 views

Voltage drop over a cell membrane

Again, a problem from exam preparation: [A] cell's membrane allows sodium ions to pass through it, but not chlorine ions. The cell is placed in a salty solution with a ten times higher ...
2
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1answer
968 views

Calculating the derivative of the average number of particles by the chemical potential

This should be a trivial calculation but somehow I have managed to get myself confused about this. The grand partition function is: $\mathcal Z = \sum_{N=1}^\infty \sum_{r(N)} {\text e}^{-\beta E_r ...
2
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1answer
549 views

Internal Energy and entropy in a open system

Here http://en.wikipedia.org/wiki/Internal_energy we can read $$U= TS-PV+\sum_i \mu_i N_i$$ Let's suppose i=1 and a ideal gas. We know: $$U=N/N_A c_v T$$; $$PV=NKT$$; $$\mu=\frac{\partial ...