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Energy density and Carnot cycle

For example, diesel has about 40 MJ/kg, what does it mean? Is that if we burn it we will get 40 MJ of energy per kg, but we can not get all of it to mechanical work? If that is the case, then why ...
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Can I take heat from the air and convert it to electricity?

Its a summer day and the air in my house has been heated up. I could switch on my air conditioning, but then I'd be using energy from the grid in order to reduce the amount of energy in my house. ...