Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. It is primarily concerned with the arrangement of electrons around the nucleus and the processes by which these arrangements change. This includes ions as well as neutral atoms and, ...

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how to count such a huge number of oscillation in atomic clock

can someone help me out please?/ actually a second is defined as time taken for 9,192,631,770 oscillations of ceasium hyperfine levels...but its not exactly that the electron moves up and down between ...
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1answer
138 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
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1answer
37 views

Drive term for a Jaynes-Cummings like hamiltonian

When reading articles on CQED or atomic physics, I often encounter the Jaynes-Cummings Hamiltonian, which in the simplistic form I will write down as: $$H = \hbar \omega_c a^\dagger a + \hbar ...
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2answers
70 views

Why does a “typical” hydrogen atom have no neutron?

There are quite a few sources (mostly high-school physics textbooks) that I've read which don't give the disclaimer that the hydrogen atom they are using in a diagram is an isotope (as in having ...
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22 views

L-S Coupling (Atomic Physics) Ground State [on hold]

Can someone please explain to me why in the second configuration the ground state is associated with $L=F=3$ and $J = 7/2 $? ** Another question: Should we always take $J$ as even? if yes, why?
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Atom Particles Relationships

I am an agriculture student, and we study tons of chemistry, and despite I took the exams I still have a good doubt on atoms. Through my studies I would say electrons are very tiny containers of ...
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2answers
69 views

Is there any atom which is dia-electric?

Take an atom. Suppose we impose some magnetic field on it. For some atoms, the energy increases---this is a phenomenon of diamagnetism. The question is, how about an electric field? Can the energy ...
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31 views

Can there be stimulated emission not in the direction of the incident light beam?

Consider a $F=1 \to F'=0$ atomic transition excited by a $x$-polarized light traveling along $z$-direction in presence of longitudinal (along the direction of the light beam) magnetic field. The ...
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2answers
265 views

How is an atom ionized by electron impact?

Can someone walk me through in detail what happens when an atom is ionized by colliding with an electron? I would prefer a solid example so I can understand it more concretely. What I think: The ...
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25 views

What does 'fully excited' actually mean?

In statistical mechanics you often hear the phrases such as 'when the degrees of freedom are fully excited then....'. An example would be the validity of the equipartition theorem. But what is the ...
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23 views

Is there any stable minus two negative ion? [duplicate]

Negative ions like H$^{-}$, He$^{-}$ are common. But, is there any negative ion with two extra electrons?
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1answer
30 views

Reaching equilibrium in a blackbody and light-matter interaction

Suppose we have a metallic cavity maintained at a fixed temperature. Suppose we start with any distribution of radiation that is not in equilibrium with the container. Gradually, when the equilibrium ...
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1answer
127 views

Excitation energy of carotene using the particle in a box model

I'm practicing for an exam and I came across the following question: The linear, conjugated π-electron system of a carotene molecule comprises 11 atoms and the distance between two atoms is 1.4 Å. ...
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How long is the surface migration length of adatoms deposited by thermal evaporation in vacuum?

The deposition of metals through thermal evaporation involves the process of adatoms migrating on the substrate before its kinetic energy decreases to a certain point or before encountering a cluster. ...
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2answers
286 views

Why does the conjugated $\pi$ bond not violate the Pauli Exclusion Principle?

Let's look at the molecule 1,3 butadiene: $CH_2=CH-CH=CH_2$ and number the carbon atoms 1 to 4 from left to right. The bonds between 1 and 2 and between 3 and 4 are double bonds: each ...
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3answers
2k views

Is there any truth to interpreting definition of a second as corresponding to oscillations?

As far as I understand the definition of a second, the Cs-133 atom has two hyperfine ground states (which I don't really understand what they are but it's not really important), with a specific energy ...
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46 views

What is the cause of discrete or quantized energy levels in an atom? [duplicate]

I understand how it is that electrons move from one energy state to another, however I've not been able to find anywhere that describes why an atom has any particular states. Why should an atom of ...
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4answers
1k views

Why does an electron shell further away from nucleus has higher energy level?

Using electrical potential energy $V=\frac{1}{4\pi \varepsilon_0} \frac{Q_1 Q_2}{r}$ , a particle further away from nucleus has lower magnitude of energy. Using Coulomb's law, a particle further away ...
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3answers
189 views
2
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1answer
77 views

Why do electrons not fully fill up all the orbitals sequentially?

Why do electrons not fully fill up all the orbitals sequentially? By this I mean: why don't the electrons fully take up the previous orbit first and then move onto the next orbit? Take calcium for ...
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1answer
37 views

Spread of the energy levels and sharp energy eigenvalues of the Schrodinger equation of the H-atom

Solving the Schroedinger equation for the H-atom (or any other system, say a particle in a box, or harmonic oscillator or anything), we obtain the energy eigenvalues are sharp with no spread. However, ...
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1answer
30 views

Why is the interaction energy of the electrons in an atom positive?

Consider a simple Hamiltonian for the Helium atom (where $e'^2 = e^2/4\pi \epsilon_0)$: ...
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1answer
33 views

Energy of photon after emission

Exercise: A hydrogen atom is at its first excited state. When it de-excites it emits a photon. What is the energy of the photon and the kinetic energy of the atom? Question: Is it correct to ...
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2answers
98 views

Density Matrix representation of excited atoms

I'd like to get an answer to this question from someone who knows his density matrix theory. I want to compare two different systems and ask how their density matrix representation looks. First look ...
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1answer
336 views

Why is the orbital angular momentum of a pi electron along the axis of two atoms' molecule one?

I'm reading quantum chemistry. The book says that the orbital angular momentum of a $\pi$ electron along the symmetry axis of a molecule made up of two atoms is $\pm 1$. I think this is a primary ...
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78 views

The calculation of the entropy of a single atom

I used to think that the entropy of a single atom could not be calculated, for in my mind only the entropy of a system containing many atoms could be calculated. But my professor told me the entropy ...
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2answers
113 views

Compton Effect Explanation

Can someone brief me about Compton effect and why does this happen? I searched everywhere read a CERN article too but couldn't understand it.
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1answer
145 views

What is the correct theoretical formula of the Hyperfine transition of neutral hydrogen (21cm line)

I found two different expressions to express the energy split of the Hyperfine transition of neutral hydrogen (21 cm line, HI) that are not equivalent, imo. from Wolfram: $$\Delta\ E= ...
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1answer
500 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
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1answer
38 views

Electron velocity in hydrogen

I was speculating over the feasibility of myon catalysed fusion. Somehow I drifted away from that a little, and I was wondering if one can find a quantum-mechanical expression for the velocity of an ...
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2answers
70 views

How does electron makes transition from one state to another?

i am not asking why it makes. i am curious about how it makes the transition. Does it go from one state to another via straight line or it makes smaller and smaller orbits till it reaches the next ...
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2answers
366 views

Is this definition of orthohelium and parahelium incorrect?

"One electron is presumed to be in the ground state, the 1s state. An electron in an upper state can have spin antiparallel to the ground state electron ($S=0$, singlet state, parahelium) or ...
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3answers
120 views

What are the original papers on the hydrogen spectral lines?

I am trying to find original sources for experiments that had observed spectral lines from hydrogen or other gases. I am looking into experiments that motivated Niels Bohr to write his ideas on the ...
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2answers
1k views

Why 2s state is lower in energy that 2p state in atoms?

The s orbital have higher probability to be closer to the core and feels larger attraction than the p orbital and on average is further away and in addition p has repulsive potentilal l(l+1)h^2/2mr^2. ...
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23 views

Higher $L$ lower energy?

For multi-electron atoms, what is the physical reason behind the fact that a higher total orbital angular momentum, $L$ gives a smaller total energy, $E$?
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412 views

Why was the Stark effect discovered much later than the Zeeman effect?

This is strange. The Zeeman effect involves the magnetic field. The Stark effect involves the electric field. In the course of classical electrodynamics, we get the impression that for many physical ...
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1answer
61 views

Relativistic correction to Hydrogen atom - Perturbation theory

Given the relativistic correction $$ H_1' = - \frac{p^4}{8m^3 c^2} $$ to the Hamiltonian (i.e. a perturbation), what does it mean when $[H_1', \mathbf{L}] = 0$? The book I'm reading says this implies ...
3
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1answer
136 views

Thomson scattering cross section: free electrons vs atoms

I am trying to find a reference for the Thomson scattering cross section difference between free electrons and atoms. I have always assumed that free electrons have a higher cross sections, but I can ...
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2answers
58 views

Can AMO physics be applicable for space travel? [closed]

I know it sounds very stupid question. I am a Ph.D student currently working on the AMO physics (Quantum Optics). I recently saw articles about the Spacex, and I thought it is really amazing, and ...
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20 views

Clarification: non-relativistic fine structure of a one-electron atom

The fine structure energy shift (in the non-relativistic limit) for a single-electron atom due to spin-orbit coupling is given by $$\Delta ...
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1answer
20 views

The energy of de-excitation

I am 10th class student and what i dont get is when electron dexcites it produces energy but what is main phenomenon which produces energy is it the motion of electron or something like disturbing ...
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1answer
44 views

What determines the color of photon that is emitted from an exited atom?

I understand the principle of how light is emitted from an atom. What I don't know is why neon atom is red and copper is green when exited? Is is the distance between the electron to protons or the ...
3
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1answer
57 views

Why do some elements burn different colors? [duplicate]

I have a torch lighter and it makes a green color when the flame passes over the metal in the center. What on the molecular level would a flame change color although there is no difference in ...
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29 views

Which Hydrogen Emission Lines Appear First?

When a blackbody is heated, it radiates photons. At low temperatures, there isn't much radiation at high-energy end of the spectrum but as the temperature raises, high-energy radiation becomes ...
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59 views

Is there a simple man's perspective of Pauli’s exclusion principle [closed]

I've been pondering over a questions from a while. Please forgive me if I am being too naive. We all know that because of Pauli's exclusion principle no two electrons can populate one state. This ...
2
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1answer
118 views

Would Hund's rules still be valid if the electron had spin 3/2?

One of my homework assignments in atomic physics was the following: Given electrons had a Spin of $S = 3/2$, what would be the number of the first 4 noble gasses (complete shells)? The obvious ...
4
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2answers
64 views

Is the conservation of angular momentum violated in electron jumps from one orbital to another?

I don't really know any quantum mechanics. But in our class, we were introduced to Bohr's model of the atom with his postulate that the angular momentum of an electron in the $n$-th orbit is ...
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2answers
78 views

Potential energy of a spherically symmetric charge density in a spherically symmetric electrostatic potential

I'm interested in calculating the potential energy of a spherically symmetric charge density in a spherically symmetric electrostatic potential. More specific, I'm currently trying to calculate the ...
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40 views

Derivation of Bohr model equations (1) in his original paper

My question is rather straightforward. In his original paper ("On the Constitution of Atoms and Molecules") Bohr provides equations (1) for the frequency and major axis orbit: \begin{align} \omega ...