3
votes
3answers
140 views

Why are hydrogen energy levels degenerate in $\ell$ and $m$?

Is there a good physical picture of why the energy levels in a hydrogen atom are independent of the angular momentum quantum number $\ell$ and $m$?
2
votes
1answer
86 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
0
votes
1answer
99 views

Is it possible to find the hydrogen atom's radial wavefunctions?

Is there a way to actually find the equation of $R(r)$ without looking at a table with these equations already given? I'm given $n$, $\ell$, and $m$.
11
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
2
votes
1answer
338 views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
3
votes
2answers
208 views

Where do mass polarization terms come from in many-body Hamiltonian? Why are they sometimes omitted?

This question is about the Hamiltonian for more than one particle (non-relativistic). Griffiths (Introduction to Quantum Mechanics, 2e) seems to imply that it is $\displaystyle ...
14
votes
8answers
2k views

Where did Schrödinger solve the radiating problem of Bohr's model?

One of the problems with Bohr's theory to describe the hydrogen atom, was that the electron orbiting around the nucleus has an acceleration. Therefore it radiates and loses energy, until it would ...
4
votes
1answer
99 views

What are relativistic and radiative effects (in quantum simulation)?

I'm reading about Quantum Monte Carlo, and I see that some people are trying to calculate hydrogen and helium energies as accurately as possible. QMC with Green's function or Diffusion QMC seem to be ...