1
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0answers
35 views

Adiabatic approximation and time-dependent problems

I am an undergraduate physics student. I have a question in approximation methods for time-dependent problems in quantum mechanics. I read the proof of the adiabatic theorem but I didn't understand ...
2
votes
0answers
41 views

Limits of integration for the radial wave function of the Hydrogen atom in the WKB approximation

I am working a problem where we have to find the energy eigenvalues for the radial wave function of the hydrogen atom for $\ell=0$ using the WKB approximation. I am sure that I set up the integral ...
1
vote
0answers
41 views

Why cannot we apply perturbation theory in Born-Oppenheimer approximation

In Weinberg's Lectures on Quantum Mechanics, he mentions Unfortunately, we cannot simply use first-order perturbation theory, with $T_{nuc}$ taken as the perturbation and the state vectors ...
3
votes
0answers
87 views

Born approximation to Lippman-Schwinger integral equation

I am having the following problem understanding the Born approximation in the case of the Lippmann-Schwinger equation. This exercise is for something which is entitled "computational physics lab ...
1
vote
1answer
65 views

The Holstein-Primakoff Representation (approximation)

I have a question regarding the Holstein-Primakoff representation. In the HP-representation we define the spin operators in terms of bosonic creation and annihilation operators. $$ S_j^+ = \sqrt{2S ...
6
votes
3answers
168 views

Finding the energy eigenvalues of Hydrogen using WKB approach

I need help to find the energy eigen values of Hydrogen atom using WKB approach. So far I know, the radial equation is given by $$\frac{1}{r^2} \frac{\partial }{\partial r} \left( r^2 \frac{\partial ...
0
votes
0answers
37 views

What is the wave function outside the barrier region?

I've been trying to learn how to apply WKB for several days now. I asked a similar question already about trying to find the wave function inside the barrier region. Now I would like to understand how ...
1
vote
1answer
164 views

How to use the WKB approximation to find wave functions?

I'm trying to learn how to apply WKB. I asked a similar question already, but that question was related to finding the energies. Here, I would like to understand how to find the wave functions using ...
1
vote
1answer
338 views

How to apply the WKB approximation in this case?

I'm trying to learn how to apply the WKB approximation. Given the following problem: An electron, say, in the nuclear potential $$U(r)=\begin{cases} & -U_{0} \;\;\;\;\;\;\text{ if } r < ...
1
vote
1answer
171 views

Schrödinger equation for many body systems

$$H_{tot}=\sum \dfrac{p_i^2}{2m}+\sum\dfrac{p_I^2}{2M_I}+\sum V_{nucl}(r_i)+\dfrac{1}{2}\sum_{i\ne j} \dfrac{e^2}{|r_i-r_j|}+\dfrac{1}{2}\sum_{I\ne J}\dfrac{z_Iz_Je^2}{|R_I-R_J|} $$ with: ...
3
votes
1answer
147 views

Self-consistent field approximation and uniform field approximation?

Can anyone give me explanation of self-consistent field approximation and uniform field approximation? I know self-consistent as when we write the Schrödinger equation as $$[ -\frac{\hbar^2}{2m} ...
1
vote
0answers
142 views

2D quantum well energy spectrum (analytical vs numerical)

I am trying to understand the energy spectrum difference between the analytical and the approximated solution for a quantum well. The particle is inside a box with domain $\Omega=(0,0)$X$(1,1)$. For ...
1
vote
3answers
1k views

Franck Condon Principle and Born Oppenheimer approximation

My question here is purely fundamental. I am confused with the concept in Franck Condon (FC) principle and Born Oppenheimer (BO) approximation. The FC principle is in accordance with the BO ...
1
vote
0answers
108 views

Measurement in Quantum mechanics

I have got a quantum conservative system whose Hamiltonian is $H$. I consider an selfandjoint operator $O$ whose eigenvalues and eigenvectors are: $$O|\psi _{n}\rangle = \lambda _{n}|\psi ...
4
votes
2answers
376 views

WKB method of approximation

Would it be legitimate to use the WKB approximation for a particle in a spherically symmetric Gaussian potential? $$V(r)~=~V_0(1-e^{-r^2/a^2}).$$ I'm not sure when to use which approximation ...
5
votes
1answer
183 views

Hawking Radiation from the WKB Approximation

Reading this paper which is itself an exposition of Parikh and Wilczek's paper, I get to a point where I fail to be able to follow the calculation. Now this is undoubtably because my calculational ...
1
vote
3answers
195 views

In solving the hydrogen atom, how to see intuitively in advance that the spin effects to the energy spectrum can be ignored?

When the hydrogen atom is solved in QM books spin is usually ignored because its effect is to add tiny piece to the energy. My question is, is there a way to see this in advance, to see that if we ...
2
votes
1answer
114 views

Are Quantum Physics and statistical theory always the same as semiclassical approximations?

Quantum Mechanics and Statistical physics is a bit hard , could we then study only the WKB approximation ? In the form: replace $ \sum_{n=0}^{\infty}exp(- \beta E_{n})=Z(\beta)\sim\iint ...
2
votes
1answer
316 views

Proof of adiabatic theorem on Wikipedia

I'm having trouble following the proof of the adiabatic theorem (apparently due to Messiah) on Wikipedia. At one stage we have: $U(t_1,t_0)=1+{1\over i}\int_{t_0}^{t_1}H(t)dt+{1\over ...
1
vote
1answer
73 views

semiclassical exact expression (in one dimension only)

let be $ N(x)= \sum_{n} H(x-E_{n}) $ the eingenvalue 'staircase' function and let be a system so $ V(x)=V(-x)$ and $ V^{-1}(x)=\sqrt \pi \frac{d^{1/2}}{dx^{1/2}} N(x) $ then would it be true that ...
0
votes
3answers
231 views

Light Rays that are Perfectly Parallel

I just heard this simple reasoning in a documentary film: Light rays from distant stars are perfectly parallel. This is pretty interesting thought. In nature, it is hard to find something really ...
4
votes
1answer
290 views

Born-Oppenheimer Approximation equivalent to Tensor-product ?

If you have a wave function $\Psi$ of a system consisting of an electron and the vibrational modes of the crystal, THEN we represent the wavefunction $\Psi%$ to be in the Hilbert Space formed by the ...
3
votes
1answer
133 views

Are energies non-transferable in the Born-Oppenheimer approximation, and when does it apply?

Adiabatic approximation or the Born-Oppenheimer approximation is used whenever the electronic motion is too fast that the electrons effectively see static nuclei and the nuclei, in turn, see an ...
3
votes
1answer
570 views

Time-Dependent Potentials in Quantum Mechanics

A potential that depends on time is usually solved using the time dependent perturbation theory in standard undergraduate textbooks in quantum mechanics. The reason usually mentioned is that time ...
2
votes
1answer
248 views

Using the Scalar Electrostatic Potential to Calculate Transition Probabilities

transition probabilites of atomic systems prone to some time-varying electromagnetic field are very often calculated using perturbation theory leading to expressions including the vector potential ...