1
vote
0answers
72 views

Adiabatic approximation and time-dependent problems

I am an undergraduate physics student. I have a question in approximation methods for time-dependent problems in quantum mechanics. I read the proof of the adiabatic theorem but I didn't understand ...
1
vote
1answer
154 views

Adiabatic approximation

The adiabatic approximation for solid state systems is rather radical. I was wondering in which cases it breaks down. As it is based on the idea of the nuclii being much heavier than the electrons I ...
2
votes
1answer
340 views

Proof of adiabatic theorem on Wikipedia

I'm having trouble following the proof of the adiabatic theorem (apparently due to Messiah) on Wikipedia. At one stage we have: $U(t_1,t_0)=1+{1\over i}\int_{t_0}^{t_1}H(t)dt+{1\over ...
3
votes
1answer
140 views

Are energies non-transferable in the Born-Oppenheimer approximation, and when does it apply?

Adiabatic approximation or the Born-Oppenheimer approximation is used whenever the electronic motion is too fast that the electrons effectively see static nuclei and the nuclei, in turn, see an ...