Thermodynamic processes that occur without exchanging heat between the system and it's environment.

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What defines the adiabatic flame temperature?

What defines the adiabatic flame temperature? In a case I have to solve, I need to describe the combustion of natural gas (Groningen natural gas, to be specific). However, I am having some problems ...
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A question about the energy of turning on and off interaction adiabatically in QFT

I read a saying as follows: In a theory with no particles which decay and no bound states, the turning on and off of the interactions merely serves to limit the effective range of forces. In this ...
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thermodynamics poisson's ratio of mixtures

air consists of 79% nitrogen and 21% diatomic gas(say) . to perform calculations on ΔH on adiabatic expansions, instead of taking as parts , can i take it as a uniform gas with some γ(poission's ...
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193 views

Comparison between isobaric, isothermal and adiabatic expansion

Please check if my understandings of these terms are right because they are a bit confusing to me. For all three types of expansions, a change in volume means work is done by the system to the ...
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190 views

Adiabatic approximation

The adiabatic approximation for solid state systems is rather radical. I was wondering in which cases it breaks down. As it is based on the idea of the nuclii being much heavier than the electrons I ...
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How to understand the indeterminate process in thermodynamics?

Consider a closed composite system with an internal movable adiabatic wall. If we release the piston, thermodynamics cannot determine the final equilibrium state (the temperature cannot be ...
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38 views

Does no variables change in an adiabatic + isothermal system?

Adiabatic + isothermal = no heat and temperature change. Does that mean the system will remain as it is? If it is adiabatic + isovolumetric or adiabatic + isobaric , is it as well no change in any ...
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How is it possible to equate the internal energy at constant volume with the internal energy of an adiabatic process?

I hope my question makes sense. My problem is that, I have read through numerous textbooks that $$nCdT = -PdV$$ (where $NC$ is constant volume) when deriving the relationship between $T$ and $V$ for ...
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Adiabatic expansion in van der Waals gas

Given a Van der Waals gas with state equation: $$\left( P+\frac{N^2 a}{V^2}\right)\left( V-Nb \right)=NkT,$$ show that the equation of an adiabatic process is: $$\left( ...
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Adiabatic Expansion with expanding control volume

I have a tube with a length $L$ and diameter $d$ that is open on 1 side. At a certain point (say $x$) from the closed end of the tube, I have a gas with a high pressure. At this point, $x$, there is ...
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Are reversible adiabatic processes always isentropic?

If my understanding is correct, neither reversible nor adiabatic processes are necessarily isentropic. But are reversible adiabatic processes always isentropic?
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primordial perturbations

According to cosmic inflation, primordial perturbations are adiabatic. As in, the fractional number density of all types of particles is the same, n_baryons = n_photons etc. But what would it mean if ...
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scattering by weak potential and the adiabatic hypothesis

In Ryder QFT, regarding the calculation of the scattering amplitude by a weak potential $V$, the potential is assumed to be switched on and off slowly using the adiabatic hypothesis. But there is a ...
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Eigenvalue of the adiabatic Hamiltonian of Farhi's three qubit 2-SAT problem

I was trying to reproduce example 3.3 of Quantum Computation by Adiabatic Evolution by Edward Farhi et. al. This is an adiabatic algorithm to solve an instance of three qubits 2-SAT problem. I think ...
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42 views

Dry adiabatic lifting

If an unsaturated air parcel ascends adiabatically in the atmosphere with an initial temperature, would the final temperature of the air parcel, when it reaches it's destination, be the same at the ...
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47 views

Isentropic process and reversibility [duplicate]

I know that every adiabatic reversible process is an isentropic process. Can a process be isentropic but still not reversible adiabatic? Please provide me some examples.
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What is the difference between reversible and irreversible adiabatic expansion?

What is the difference between reversible and irreversible adiabatic expansion? Is it true that the work done by the gas is the same but the pressure applied externally differ between two process? ...
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Difference between non-adiabatic coupling and diagonal Born Oppenheimer correction?

I think my question is quite well formulated in the title! I'm trying to understand collision process involving crossing between different electronic states in the potential energy surface, which ...
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Steady-state adiabatic nozzle, unknown exit velocity & temperature [closed]

The question is 2.10 taken from: Introductory Chemical Engineering Thermodynamics, 2E by Elliot,Lira Air at 30ºC and 2MPa flows ata steady state in a horizontal pipeline with a velocity of 25m/s. ...
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Is it possible to change one quantum state to another state by a cyclic adiabatic process?

An example is applying magnetic flux through the axis of a cylinder (2D system with periodic boundary condition). When changing flux from 0 to 1 flux quanta adiabatically, it seems that we can ...
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Can we apply $pV^\gamma$=const only for quasistatic adiabatic process?

But If this is so, I have often seen people applying this formula for quick processes where no heat exchange is possible. Here is an example from where I am quoting the following: we will assume ...
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290 views

Does the entropy of an adiabatically isolated system stays the same after we decrease/increase the pressure?

Even if the system is isolated and there is no heat exchange with surroundings, shouldn't the decrease/increase of pressure result in increase/decrease of entropy? Does this property of an ...
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The notion of an adiabatic process in thermodynamics -vs- quantum mechanics

I'm confused about the terminology in the two contexts since I can't figure out if they have a similar motivation. Afaik, the definitions state that quantum processes should be very slow to be called ...
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Different forms of the Adiabatic Theorem

I've been reading several papers on Adiabatic Quantum Computation, and I am confused by the form in which the adiabatic approximation condition is presented. For example (quant-ph/0001106 eq 2.8) ...
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Schrodinger basis kets with Time-dependent Hamiltonian

I was reading through the proof of the Adiabatic Theorem (in Sakurai) and I realised I'm not quite sure how Schrodinger Basis kets behave when we have a time-dependent Hamiltonian. I know that with a ...
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How do you calculate the change in temperature of an adiabatic system?

I really don't even know how to start doing this problem. I understand PV=nRT and I understand that if either T, V, or P is kept constant, then the other 2 change at the same rate, and I understand ...
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Adiabatic expansion in the atmosphere

When an air parcel rises and cools adiabatically, it is said that there is no heat transfer as work is done on the surrounding atmosphere as the parcel expands. The parcel loses internal energy and ...
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How do spin orientations change during adiabatic demagnetization of paramagnet?

Suppose a paramagnetic solid is taken on the following cycle, where $B_1 > B_2$ (1)->(2)->(3) I'm trying to explain what happens to occupation numbers in magnetic levels. Step (1) As $B_1$ ...
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Formula for molar specific heat capacity in polytropic process

I found this formula for a polytropic process, defined by $PV^n = {\rm constant}$, in a book: $$C = \frac R{\gamma-1} + \frac R{1-n} $$ where $C$ is molar specific heat and $\gamma$ is adiabatic ...
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Why is adiabatic process isentropic?

I have read that adiabatic process is isentropic because there is no heat exchange in an adiabatic process and thus no change in entropy. But my question is - Even in adiabatic process, work can be ...
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Adiabatic approximation and time-dependent problems

I am an undergraduate physics student. I have a question in approximation methods for time-dependent problems in quantum mechanics. I read the proof of the adiabatic theorem but I didn't understand ...
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180 views

How do you explain the fact that when air expands freely into an evacuated chamber from a constant pressure atmosphere, its temperature increases?

I came across this paper: Baker, B. (1999). An easy to perform but often counterintuitive demonstration of gas expansion. American Journal of Physics, 67(8), 712-713. ...
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How is this process not quasi-static yet reversible?

Consider a (adiabatic) canister with a piston containing some gas kept in a vacuum. There are two weights on the canister which equalize the pressure of the gas on the piston. Assume the system is at ...
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Why does a gas get hot when suddenly compressed? What is happening at the molecular level?

My guess is that the molecules of gas all have the same speed as before, but now there are much more collisions per unit area onto the thermometer, thus making the thermometer read a higher ...
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Basic Thermodynamics: Quasistatic Adiabatic Process

I'm going through the exercises in a Thermodynamics book, just to revise and build my intuition. Right now, I'm working on: Show that for a quasistatic adiabatic process in a perfect gas, with ...
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Adiabatic process of an ideal gas derivation

I am working through the derivation of an adiabatic process of an ideal gas $pV^{\gamma}$ and I can't see how to go from one step to the next. Here is my derivation so far which I understand: ...
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Function describing an adiabatic process

I understand that an isothermic process, plotted on a PV diagram, can be described by a rectangular hyperbola. However, now I am wondering, what about an adiabatic process, what function best ...
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Work of an adiabatic/ compresion: sign?

As far as I am concerned the adiabatic work it is given by: $$ W_{adi}=\frac{P_{f}V_{f}-P_{i}V_{i}}{\gamma -1}$$ While I have seen in other examples that it is used with $1-\gamma$ in the ...
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How does this argument imply that entropy does not change in a quasi-static adiabatic process?

I am working through some notes of Gould and Tabochnik here and I am confused by their argument showing that entropy does not change in a quasi-static adiabatic process. First, entropy is defined to ...
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Ideal gas law, pressure increase and temperature

If I had a container, full with air, and I suddenly decreased the volume of the container, forcing the air into a smaller volume, will it be considered as compression, will it result in an increase in ...
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742 views

Adiabatic proccess and Carnot cycle in a photon gas

I am making a comparation between the photon gas and the ideal classic gas for my Thermodynamics class. The photon gas is defined by the equations: $$U=aVT^4 $$ $$P=\dfrac{1}{3}aT^4$$ I found this ...
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128 views

Sign Paradox in Berry's Phase

Suppose we have normalized states $| n(\vec{R})\rangle$ indexed by continuous variable $\vec{R}$. Then fixing our choice of gauge and ignoring dynamic phase, the phase difference between two states ...
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Adiabatic evolution for initial Hamiltonian on Hadamard basis and problem Hamiltonian as diagonal

This is spawned from a comment at the answer to one of my previous questions. Someone suggested to me that claiming the following statement might be NP-hard. Could anyone please help me to figure out ...
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Confusion about a lemma on the time constraint of an adiabatic evolution (arXiv:quant-ph/0604077)

I am going through the paper Quantum adiabatic evolutions that can't be used to design efficient algorithms by Zhaohui Wei and Mingsheng Ying. On the second page they prove a lemma. The statement goes ...
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Why is there a sign error in my derivation? Adiabatic expansion of ideal gas: $TV^{1-\gamma}$ is constant

This is the last part of a derivation of the equation for an ideal gas undergoing reversible adiabatic expansion. I'm trying to prove that $T V^{\gamma-1}$ is constant, but my result is that $T ...
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560 views

Adiabatic filling of a container

Suppose a thermally insulated container is filled with atmospheric air until the pressure reaches 5000 psi. This could represent the filling of a diving cylinder, before thermal dissipation becomes ...
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Adiabatic quantum Hamiltonian of variable dimension

Is adiabatic quantum Hamiltonian of variable dimension possible? This is very hypothetical and I am afraid may not have enough merit to belong to this forum. I would still like to elaborate. Here is ...
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Adiabatic theorem in the regime of quantum optics

I am wondering whether there is a version of adiabatic theorem in the regime of quantum optics. My understanding of quantum optics involves with the interaction between photon and atom. This ...
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Intuition behind Hamiltonian

I am reading this paper by Das et al. which converts Deutsch's algorithm into an adiabatic quantum algorithm. I don't get the intuition behind the initial and final Hamiltonians. If defines the ...
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What is the energy scale of a Hamiltonian?

On the second page of this paper a term 'fundamental energy scale' is used while talking about a Hamiltonian. The context is implementing Deutsch's algorithm using Adiabatic Quantum Computation. What ...