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Bohr's second postulate in Bohr model of hydrogen atom deals with quantisation of angular momentum.But, I was wondering why he quantised angular momentum and any other quantity?

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Bohr didn't start by quantizing the angular momentum. He started by requiring that there exists discrete orbits and that the energy of photons released met the plank condition. Quantized angular momentum was a result he derived in the paper. And yes, most intro textbooks use $L=n\hbar$ as the launching point in discussing the Bohr atom, but it was not Bohr's assumption which was rather simpler. I'll find a reference if I can. –  dmckee Nov 14 '13 at 15:05

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up vote 10 down vote accepted

Bohr postulated that electrons orbit the nucleus in discrete energy levels, and electrons can gain and lose energy by jumping between energy levels, giving off radiation of frequency $\nu$ according to the formula

$\Delta E = E_2 - E_1 = h\nu$

where $\nu = \frac{1}{T}$, where T is the period of orbit, as in classical mechanics.

Now during the transition, let $r$ be the average radius and $v$ be the average velocity of the particle. Making such a simplification allows us to calculate the period of orbit:

$T = \frac{2\pi r}{v}$


$\Delta E = h\nu = \frac{hv}{2\pi r}$ (1)

Also, we know the kinetic energy at a particular energy level is given by:

$KE = \frac{mv^2}{2} = \frac{Lv}{2r}$, and therefore,

$U = 2KE = \frac{Lv}{r}$

Again, taking $r$ and $v$ to be the average radius and velocity during the transition, we get:

$\Delta E = \frac{(L_2 - L_1)v}{r}$ (2)

Equating (1) and (2) gives,

$\frac{(L_2 - L_1)v}{r} = \frac{hv}{2\pi r}$


$L_2 - L_1 = \frac{h}{2\pi} = \hbar$

Therefore, each energy level differs from the next by an angular momentum of $\hbar$. It is therefore reasonable to postulate that if the lowest energy level has no angular momentum, then each energy level from then on has an angular momentum of $n\hbar$ where $n$ is an integer.

Below is the modern de-Broglie method:

From the definition of angular momentum,

$L = rp$, where L is angular momentum, r is radius of orbit and p is momentum.

We also know that momentum is related to wavelength of a particle from the de-broglie relation:

$p = \frac{h}{\lambda}$

Combining these gives:

$L = \frac{rh}{\lambda}$

Ok, now let us consider an electron orbiting a nucleus.

The circumference of the orbit is $2\pi r$, and because we want the electron to form a standing wave orbit, we require that $\frac{2\pi r}{\lambda}$ be an integer, in order for the wave not to interfere with itself. That is,

$\frac{2\pi r}{\lambda} = n$, where $n$ is some integer.

Now we can substitute our definition of $L$ from above into this equation to give:

$\frac{2\pi L}{h} = n$

and re-arranging gives,

$L = \frac{nh}{2\pi} = n\hbar$

Therefore, quantising angular momentum allows for the electron wave to not intefere with itself during orbit.

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As dmckee commented, angular momentum is barely mentioned in Bohr's revolutionary 1913 paper "On the Constitution of Atoms and Molecules" (Philos. Mag. 26 , 1).

Instead, Bohr's bases his argument on Planck's hypothesis that the radiation from a quantum harmonic oscillator "takes place in distinctly separated emissions, the amount of energy radiated out from an atomic vibrator of frequency" $\nu_o$ "in a single emission being equal to" $nh \nu_o$, with $n$ a whole number and $h$ Planck's constant. (I've changed some of Bohr's notation to conform with modern usage.)

Now a harmonic oscillator has the same frequency no matter what its energy, but not so a hydrogen atom.

After calculating the relation between frequency $\nu_c$ and ionization energy $W$ for a classical closed orbit of semi-major axis $a$, charge $e$, and electron mass $m$:

$$ \nu_c = \frac{1}{\pi} \sqrt{\frac{2}{m}} \frac{W^{3/2}}{e^2} \quad , \quad 2a = \frac{e^2}{W}$$

Bohr offers two approaches:

  1. Consider an electron starting at rest, far from the atom, and ending in a stable closed orbit (itself a bold assertion, since classically there are no such orbits). Since the starting "frequency" is 0, Bohr splits the difference and postulates that the radiated emission's frequency $\nu_r$ is half the frequency of the end orbit $\nu_c$. Setting $W=h \nu_c/2$ (the energy radiated away), Bohr derives explicit expressions for the end orbit characteristics.
  2. As an alternative, Bohr considers transitions between two nearly classical orbits of very low frequency, where the start and end orbit frequencies are nearly identical. This situation is very similar to the harmonic oscillator, so the Planck hypothesis can be applied directly: the radiation frequency equals the orbit frequency. The results are consistent with the first approach.

Only then does Bohr note: "While there obviously can be no question of a mechanical foundation of the calculations given in this paper, it is, however, possible to give a very simple interpretation of the result", namely the stable circular orbits have quantized angular momentum $L=n \hbar$.

By 1918, in "On the Quantum Theory of Line-Spectra", Bohr has adopted the technique of adiabatic invariants to demonstrate that the action $I$ of a hydrogen atom is quantized just like the harmonic oscillator: $I=nh$. He notes that "this condition is equivalent with the simple condition that the angular momentum of the particle round the centre of the field is equal to an entire multiplum of $h/(2 \pi)$.

I think "multiplum" = "multiple".

It took awhile to appreciate the fundamental nature of quantized angular momentum.

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