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Long ago I learned that a plasma was a distinct state of matter after solid, liquid and gas, and also that it was achieved by imparting heat to a the matter. But most references describe a plasma as an ionized gas. So I'm having trouble understanding, what then, does it mean to be a distinct phase of matter? Is ionization, as opposed to heat, all that's required to make a gas a plasma? If so, what makes a plasma more distinguished than, say, an ionized liquid?

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If you start with a liquid and start heating it, it will vaporize before it ionizes. –  Ben Crowell Oct 2 '13 at 22:42
A plasma is when the material is so hot that the electrons move so fast that they no longer stay bound to a particular nucleus. You sortof have a soup of nuclei and electrons without distinct complete atoms. By the way, you left out the fifth state of matter. –  Olin Lathrop Oct 2 '13 at 22:48
Possible duplicate: physics.stackexchange.com/q/12760/2451 –  Qmechanic Oct 2 '13 at 22:57

3 Answers 3

up vote 5 down vote accepted

For clarity, there is a common misconception about plasma here. Plasma when being introduced for the first time to someone who doesn't know what it is, it is called "The fourth state of matter" which is an inaccurate description of it. Since this term is used for introducing some one to plasma, it is no big deal.

When a material changes from a distinct phase to another, it goes through a physical process called phase transition. When gas becomes plasma, it doesn't go through the standard phase transition. Hence plasma-in a general sense-can't be regarded as a distinct phase as solid, liquid and gas phases. It is a phase of the gaseous state. In certain rare cases however, transition from gas to plasma can be described as phase transition.

Plasma by definition is a mixture of free electrons and their ions (possibly negative ions). You need enough energy to liberate electrons from atoms. Roughly speaking, When you put that energy in a solid, energy might be dissipated as heat. If you put that energy in a liqued, energy might be dissipated in vaporization. If you put it in a gas it goes into breaking atoms and molecules (creating plasma). The following figure makes it clearer

enter image description here

Hopefully that was useful

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Very helpful, thanks! –  Chroma Geddon Oct 3 '13 at 17:40
I'm not so sure that plasma doesn't deserve a spot as a separate state of matter simply because ionization and recombination does not happen at a single temperature. Plasma does have a well-defined degree of ionization, and its properties are fundamentally different than all other states of matter. See @ChinYeh's answer. I have several plasma physics textbooks that explicitly call it a fourth state of matter. In some sense, this question is similar to "is Pluto a planet?", but I think it's important to draw more attention to the properties of the state than to its transitions. –  Paul Mar 14 '14 at 20:00
Just a nitpick - can't we avoid the liquid-vapor phase transition in e.g. water by going around the critical point in temperature-pressure space? So if avoidance of a proper phase transition is sufficient to declare plasma the same phase as gas, doesn't that also mean liquid is part of that same phase? This is probably pushing the definition further than it was intended, but it's something to think about. –  Chris White Jun 27 '14 at 16:23

Plasma is said to be a distinct phase because it does not observe the usual description and physical laws that are used to describe the usual 3 states of matter, on several counts:

  • Plasma is not in equilibrium. Often it is far from an equilibrium. Therefore, thermodynamics can't be used to explain.
  • Plasma is made of loose particles, but these particles do not follow kinetic theory of gases. Ideal gas law is not even a first approximation to model a plasma.
  • Plasma particles do not follow a statistical velocity distribution (Maxwell distribution).
  • Plasma must have two (or more) independent components. These components must carry charges. one is made of electrons, the other cations. It's electrons that are more active in deciding plasma properties.
  • Unlike in gases, liquids, and (molecular) solids, plasma particles exert strong forces to each other.
  • There is not a single temperature that characterizes plasma. This means two things. One, plasma is not a clear-cut phase, hence, there is not a clear-cut phase transition temperature, like melting or boiling, for plasma. Two, one temperature may not be enough to describe a plasma. The temperature for electrons may often be higher than that for the rest of plasma.
  • Plasma can be confined by magnetic force (does not need a container wall).
  • Unlike other 3 states, plasma is mostly unstable.

In the latter part, you have two questions which amounts to "What makes plasma a plasma?" Ionization is required to form a plasma, but there is no specific temperature requirement. Plasma can exist in interstellar space at around 100 K and in controlled laboratories at close to 0 K. The degree of ionization is usually represented as the ratio of charged ions to total (charged plus neutral) nuclei in a gas, and only a small degree of ionization (sometimes below 1%) is enough to make a gas behave like a plasma.

To be clear, a plasma is not the same as an ionic fluid, which is not a result of ionization but rather is made of cations and anions. Ionization means that electrons are set free from atoms or molecules. An ionic fluid is a salt in a liquid state.

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Except plasma was the first state of matter, not the forth. All matter formed from plasma, it is not converted from matter to plasma, but from plasma to matter. This is why 99% of the universe is plasma. The electrons were never stripped from the atoms, they never were part of the atom until they are bound by the electrical energy in the plasma to form gasses, liquids and solids.

http://home.web.cern.ch/about/physics/heavy-ions-and-quark-gluon-plasma "For a few millionths of a second, shortly after the big bang, the universe was filled with an astonishingly hot, dense soup made of all kinds of particles moving at near light speed. This mixture was dominated by quarks – fundamental bits of matter – and by gluons, carriers of the strong force that normally “glue” quarks together into familiar protons and neutrons and other species. In those first evanescent moments of extreme temperature, however, quarks and gluons were bound only weakly, free to move on their own in what’s called a quark-gluon plasma"

And supposedly after 13+ billion years, only less than 1% of of that plasma has bonded into solids, liquids and gasses. The rest has bonded into a mixture of ions and electrons, condensed from that quark/gluon state.

To look at it as being formed from solids, liquids and gasses is an incorrect viewpoint, not supported at all by science. Solids, liquids and gasses are instead formed from plasma.

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I don't think the time ordering is the issue here - I'm sure everyone agrees you can go both ways. Also, while the universe started out as a plasma, most of the material became neutral gas at recombination a few hundred thousand years after the big bang. It was then reionized a few hundred million years later. –  Chris White Jun 27 '14 at 16:15
This doesn't really seem to answer the question. –  Kyle Kanos Jun 27 '14 at 16:33

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