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I have this homework question:

"Show that any reversible engine operating between T1 and T2 is a carnot engine."

I think I have a solution, but it feels very hand-wavy. We know that any process that can be represented as a loop in the PV plane is reversible as the net entropy change will be zero. We must operate between two specifice temperatures, so the loop must comprise of two isotherms a T1 and T2. So the question is what curves join the isotherms. As a heat engine comprises of energy input at constant temperature, there will be no energy change between the isotherms. So the curves connecting the isotherms must be adiabatic curves. So we have a carnot cycle.

Is this sufficient? I don't know why, but I doubt it.

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I suspect the expression "operating between T1 and T2" actually means "operating between heat reservoirs with temperatures T1 and T2". But even then I am not sure "any reversible engine operating between heat reservoirs with temperatures T1 and T2 is a Carnot engine." As far as I know, a Carnot engine is an engine "that operates on the reversible Carnot cycle" (http://en.wikipedia.org/wiki/Carnot_heat_engine ), which cycle consists of two isothermal processes and two adiabatic processes. However, it seems that more complex reversible processes can exist that use the same isothermal processes (but maybe different parts of them) and more than two adiabatic processes (e.g., T1S1-T1S2-T2S2-T2S3-T1S3-T1S4-T2S4-T2S1-T1S1). so maybe the condition of the problem lacks some additional requirement.

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The Carnot cycle is the unique reversible cycle working between two reservoirs of temperature $T_1$ and $T_2$, such that when the engine is in contact with reservoir 1, evolution is isothermal at temperature $T_1$, isothermal at $T_2$ when the engine is in contact with reservoir 2 and adiabatic (isentropic) elsewhere. There are no other possibilities with these "boundary conditions" i.e. interface to the outside World.

However, there are many other possibilities for the interface to the outside World. The engine could make contact with many more than two different temperature reservoirs during a cycle, or heat could be added at constant volume (e.g. from detonation of a chemical reaction inside a rigid vessel, as approximately happens during a Diesel cycle).

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Should I infer from the last para that there exists such arbitrary reversible non-Carnot engine which operates between more than two temperatures? If so, how would then efficiency be defined? Efficiency is defined for engines working between two temperatures in all the literatures I'm accustomed with. How would we define efficiency for such an engine operating between more than two temps. and would it still be less than Carnot's which operates between two temps? – MAFIA36790 Jun 13 at 3:38

Another way to show this is through the non-existence of perpetual motion, the Feynman way. As he says, we first assume that perpetual motion and hence the creation of energy is not possible. Next, let engine $A$ be a reversible engine working between temperatures $T_1$ and $T_2$ where $T_1>T_2$ and let it absorb heat $Q_1$ frome the reservoir at $T_1$ and give out heat $Q_2$ at reservoir at temperature $T_2$ doing work $W=Q_1-Q_2$ in the process.

Consider another reversible engine $B$ working between the same temperature but having different efficiency. On taking heat $Q_1$ from the hotter reservoir, let us suppose it does work $W'>W$ and therefore gives out heat $Q'$ at the colder reservoir which is less than $Q_2$. After operating engine $B$ for one cycle, we could use $A$ in reverse to siphon out $Q_2$ from colder reservoir, submit heat $Q_1$ at the hotter reservoir with a work input of $W$. But since $W'>W$, therefore the net result of oprating $B$ followed by reverse $A$ will be to have drawn heat $Q_2-Q'$ from the colder reservoir and completely converted it into work $W'-W$, without any other change or entropy since the engines are reversible. But this contradicts the well know statement of second law of thermodynamics:-

Clausius staement-"Heat can never pass from a colder to a warmer body without some other change, connected therewith, occurring at the same time."

This argument shows that working between any two temperatures, irrespective of the nature of the engine, a reversible engine shows the maximum efficiency and all reversible engines must show the same efficiency (Carnot principle) to not violate second law of thermodynamics. This idea, originally Carnot's proves that all reversible engines have the same efficiency as a Carnot engine. Your argument uses certain assumption about the working of a reversible engine which might not be universally true.

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Thanks for the detailed response. What exactly am I assuming that "might not be universally true"? – Kieran Cooney Sep 20 '13 at 3:37
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@KieranCooney You are assuming that there are only four quasistaic processes in a reversible engine, but that is not true. You can design a reversible engine which performs several transitions, which may not be adiabatic and isothermal only. You may use a complex setup with several compartments and mechanical constraints which would ultimately complicate the PV loop of the system by including several processes unlike only 4 used in Carnot engine. But if it is reversible and operates between 2 reservoirs at different temperatures, it's efficiency must be = to Carnot efficiency. – Satwik Pasani Sep 20 '13 at 7:01

Clausius' statement about heat not being able to flow spontaneously from a cold body to a warm body is sufficient to prove that no engine can have an efficiency greater than that of a perfectly reversible engine. But it's not enough to prove that the Carnot engine is the only reversible engine. For example, there could be a perfectly reversible engine where the gas at initial volume $V_1$ and temperature $T_1$ draws heat from a hot reservoir, expands doing work against constant pressure till the gas reaches a higher temp $T_2$, then makes contact with a cold reservoir to contract isochorically to a lower temperature $T_3$ and lower pressure $P_2$, then makes contact with an even colder reservoir to bring down the temperature isobarically until the volume contracts to the original volume $V_1$, and then makes contact with a hot reservoir to heat up isochorically back to temperature $T_1$ (the original state). This seems to be as reversible an engine as the Carnot engine. The only difference is that here more than two heat reservoirs are involved. In fact, a Carnot engine is the only possible engine which can operate between just two temperatures; all other engines require one or more heat source or heat sink at some intermediate temperatures. This has a bearing on the issue and make the two not comparable. It can be graphically demonstrated that, between the two outermost temps (i.e. between the maximum and minimum temperatures), the Carnot engine is the most efficient - see this excellent video.

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