Fourier transform of the Coulomb potential

Question

When trying to find the Fourier transform of the Coulomb potential

$$V(\mathbf{r})=-\frac{e^2}{r}$$

one is faced with the problem that the resulting integral is divergent. Usually, it is then argued to introduce a screening factor $e^{-\mu r}$ and take the limit $\lim_{\mu \to 0}$ at the end of the calculation.

This always seemed somewhat ad hoc to me, and I would like to know what the mathematical justification for this procedure is. I could imagine the answer to be along the lines of: well, the Coulomb potential doesn't have a proper FT, but it has a weak FT defined like this …

Edit: Let me try another formulation:

What would a mathematician (being unaware of any physical meanings) do when asked to find the Fourier transform of the Coulomb potential?

Answer 1

It can be justified using distribution theory.

Answer 2

I think you need this integral $$\int {\frac{1}{{\left( {2\pi } \right)^3 }}\frac{{e^{i\vec k \cdot \vec r} }}{{k^2 + a^2 }}d^3 \vec k} = \frac{{e^{ - ar} }}{{4\pi r}}$$ We suppoes initially that $a \ne 0$. If we use polar coordinates with $\vec k$ in the z-axis we have: $$\int {\frac{1}{{\left( {2\pi } \right)^3 }}\frac{{e^{i\vec k \cdot \vec r} }}{{k^2 + a^2 }}d^3 \vec k} = \frac{1}{{\left( {2\pi } \right)^3 }}\int\limits_0^\infty {\frac{{k^2 }}{{k^2 + a^2 }}dk} \int\limits_0^{2\pi } {d\varphi } \int\limits_{ - \pi /2}^{\pi /2} {\cos \theta e^{ikr\sin \theta } } d\theta = $$ $$ = \frac{1}{{\left( {2\pi } \right)^2 }}\int\limits_0^\infty {\frac{{k^2 }}{{k^2 + a^2 }}dk} \int\limits_{ - 1}^1 {e^{ikrx} dx} = \frac{2}{{\left( {2\pi } \right)^2 }}\int\limits_0^\infty {\frac{{k^2 }}{{k^2 + a^2 }}\frac{{i\sin \left( {kr} \right)}}{{ikr}}dk} $$ $$ = \frac{1}{{\left( {2\pi } \right)^2 }}\frac{1}{r}\int\limits_{ - \infty }^\infty {\frac{{k\sin \left( {kr} \right)}}{{k^2 + a^2 }}} dk$$ It is the immaginary part of: $$ \frac{1}{{\left( {2\pi } \right)^2 }}\frac{1}{r}\int\limits_{ - \infty }^\infty {\frac{{ke^{ikr} }}{{k^2 + a^2 }}} dk = \frac{1}{{\left( {2\pi } \right)^2 }}\frac{1}{r}2\pi i\frac{{iae^{ - ar} }}{{2ia}} = \frac{1}{{4\pi r}}e^{ - ar} i$$ so: $$\int {\frac{1}{{\left( {2\pi } \right)^3 }}\frac{{e^{i\vec k \cdot \vec r} }}{{k^2 + a^2 }}d^3 \vec k} = \frac{1}{{4\pi r}}e^{ - ar} $$ The unique singular point inside the circumference is $k=ia$. We now determine the case $a=0$. We have: $$\int {\frac{1}{{\left( {2\pi } \right)^3 }}\frac{{e^{i\vec k \cdot \vec r} }}{{k^2 }}d^3 \vec k} = \frac{1}{{\left( {2\pi } \right)^2 }}\frac{1}{r}\int\limits_{ - \infty }^\infty {\frac{{\sin \left( {kr} \right)}}{k}} dk = $$ $$\frac{1}{{\left( {2\pi } \right)^2 }}\frac{1}{r}\int\limits_{ - \infty }^\infty {\frac{{\sin t}}{t}dt = \frac{1}{{4\pi r}}} $$

Answer 3

If the final result is unique and independent of the regularization method, then it is a mathematically correct answer.

Answer 4

Dear Emerson, the "weak Fourier transform" of the potential, which is simply $4\pi / q^2$, is the "proper physical" value of the Fourier transform.

In physics, it simply makes no sense to say that a Fourier transform "doesn't exist": the Coulomb potential clearly does exist, and when we're calculating something that depends on its Fourier transform, the answer also has to exist because the world has to behave in some way. It's just generally impossible in physics to say that a valid theory produces an "ill-defined answer". We must always struggle to get an actual, well-defined answer.

And quantum electrodynamics, even though it has a superficially divergent Fourier transform of the Coulomb potential, is an excellent theory. Still, we need the Fourier transform to answer many questions. So the only question can be how to find out the right answer - not whether an answer exists. Of course that it does. The physically correct answer is most easily obtained by regulating the potential - as a limit of the Yukawa potential - and by exchanging the limit with the integration in the middle of the calculation, to guarantee that the result is sensible.

This is like giving a mass to the photon - we call it an infrared regulator. Such things are omnipresent in quantum field theory. If an expression doesn't naively make sense, one tries to express it as a limit of a more general expression, and calculate a more general calculation, which is more well-defined, and try to take the required limit at the very end. This is the right physicist's approach to seemingly ill-defined expressions and it always leads us out of the trouble and it always tells us something more meaningful.

A failure - a refusal to calculate the answers - is just not acceptable in physics.

Answer 5

I'm not sure that a justification is required.

We don't feel the need to justify solutions obtained by making a change of variables, nor those obtained by differentiating under the integral sign, nor those obtained by analytic continuation and application of contour integrals and so on for a host of other tricks of symbol manipulations.

But if you insist...

You can interpret this as the potential due to a massive scaler boson (the Yukawa potential), and then take the limit of vanishing mass.