(1)
A physical interpretation of Riemann Invariants is only possible for an isentropic flow. For this case, there are two families of characteristics
$$
\frac{dx}{dt}=u+c\\
\frac{dx}{dt}=u-c\\
$$
where $u$ is the local gas speed and $c$ is the local sound speed.
The two characteristics represent the left and right going waves.
The Riemann invariants for such a case are given by:
$$
u+\frac{2c}{\gamma-1}=r \mbox{ along }\frac{dx}{dt}=u+c\\
u-\frac{2c}{\gamma-1}=s \mbox{ along }\frac{dx}{dt}=u-c\\
$$
$r$ and $s$ are the Riemann invariants. Now notice what this statment is saying.
Consider a right going wave. The Riemann invariant tells you that $u$ and $c$
can't change arbitrarily. They have to change in such a way that when we
add $u$ to $\frac{2c}{\gamma-1}$, we recover the constant $r$. That is
why they are also called compatability conditions.
When entropy is involved for an non-isentropic flow, the Riemann invariants
become complex and will no longer have a simple interpretation. To see this,
you need to see the derivation of the Riemann Invariants in standard Gas
Dynamics books like Anderson, Compressible Flow or Shapiro.
(2) could you clarify your second question and what you are trying to do?
cheers, abiyo