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Surely, upon an increase in temperature, the atoms within the thermistor would vibrate with more energy and therefore more vigorously, hence making the electrons flowing through the electric circuit more likely to collide with one of the atoms, so increasing resistance.

However, the effect of temperature on a thermistor is contrary to this. I can't understand how it can be.

It's analogous to running across a playground: if everyone is still you're less likely to collide with someone, however if everyone is constantly moving from left to right then a collision is more likely.

So why does an increase in temperature decrease the resistance of a thermistor?

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2 Answers 2

up vote 7 down vote accepted

Thermistor with this particular temperature behavior are commonly semiconductors. In a semi-conductor, there is an energy gap between the (filled) valence and the (empty) conduction band. At zero temperature, no charges are in the conduction band and the resistance should be infinite as the system behaves basically like an insulator.

If you turn on the temperature, some electrons will start to occupy the conduction band and thus contribute to conduction, lowering the resistivity.

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Using your playground example....

Imagine if you had to pass a message (electricity) across the playground, when cold you would have to stretch between each fixed person to pass this message. When hot, more people fill the gaps, the message is easier to pass.

Hope this helps :)

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