I don't have the book here right now, so I am not sure what he is referring to exactly by that comment. But by modifying the energy-momentum tensor, you will change the central charge and actually get a whole new CFT. So I would not call that a symmetry of the free scalar theory.
However the theory does have a lot more symmetry, let me focus on one chiral sector only. As you know already, the special feature of two-dimensional CFT's is that the spin-two conserved current (EM-tensor) $\bar{\partial}T(z)=0$, automatically implies that there is an infinite number of conserved currents $\bar{\partial}(z^n\,T(z)) = 0$ in the theory. This is essentially the reason why the conformal algebra, extends to the infinite-dimensional Virasoro algebra i two-dimensions. Lets use the notation $W_2\equiv T$, where the index refers to the spin.
Free-field theories, however, contain an infinite tower of higher-spin conserved currents $W_s(z)$ where $s= 2, 3, \dots$ is the spin. Similar to the $W_2$ case, for any conserved current $W_s$, there is infinite number of associated conserved currents $\bar{\partial}(z^n\, W_s(z))=0$. Thereby each current $W_s$ extends the Virasoro algebra with infinite number of new generators, and there is by itself an infinite number of currents $W_s$. So this is a vast extension of the Virasoro algebra.
For example in the case of free complex scalar theory the currents are given by [A]
$W_s(z)= B(s)\sum_{k=1}^{s-1}(-1)^k\, A^s_k\, :\partial^k\phi\,\partial^{s-k}\bar{\phi}:(z)$,
where $B(s)$ and $A^s_k$ are constants. See in particular equations (2.11) and (2.18a)-(2.18e) in [A]. Here $W_2(z)$ is the usual energy-momentum tensor leading to $c=2$ and the Virasoro algebra. All the generators combined give rise to the so-called $w_\infty^{PRS}$-algebra, which contain the Virasoro algebra as a "small" subalgebra. Similar things can be done for other free-field theories, I myself used a similar construction for the free ghost system in a recent paper.
Higher-spin extensions of the Virasoro algebra are usually called $\mathcal W$-algebras and they do not lead to conventional Lie algebras, but certain types of non-linear algebras. See [B] for a review. The free field theories realize the rare type of $\mathcal W$-algebras which are usual (linear) Lie algebras.
In higher dimensions free-field theories also have an infinite tower of higher-spin conserved currents and thereby an infinite dimensional symmetry algebra. But each conserved current only lead to a finite number of generators in the algebra, unlike the the two-dimensional case.
Maybe Polchinski is referring to this vast number of higher-spin symmetries of the free-field theories?
[A]: Bakas and Kritsis - Bosonic realization of a universal $\mathcal W$-algebra and $Z_{\infty}$ parafermions [Nucl. Phys. B 343, 185 (1990)]
[B] Bouwknegt and Schoutens - $\mathcal W$ symmetry in conformal field theory [Phys.Rept. 223 (1993) 183-276]