Suppose I have an electron. There are various states it could be in. The states where we have a definite spin component are
$|z_{UP}\rangle$
z component of its spin is pointing upwards
$|z_{DOWN}\rangle$
z component of its spin is pointing downwards
$|x_{RIGHT}\rangle$
x component of its spin is pointing to the right
$|x_{LEFT}\rangle$
x component of its spin is pointing to the left
(we'll ignore the y direction). Now a Stern Gerlach apparatus gives us a means for measuring these spin components - if we orient the apparatus in the z plane its powerful magnets separate incoming electrons so that the ones it's measured as z-spin-up go upwards and the ones as z-spin-down go downwards.
Now suppose I have an incoming beam of electrons, where I've prepared them so that 50% of them are z-spin-up and 50% are z-spin-down. (I could do this by using a previous Stern Gerlach apparatus, measuring the z spins then recombining the beam). This is a mixture, not a superposition. If I now do my z measurement, I find 50% in z-spin-up and 50% in z-spin-down as I expect.
If, instead of the mixture, my electrons are in a true superposition state, say $$ \frac{1}{\sqrt{2}}(|z_{UP}\rangle + |z_{DOWN}\rangle)$$ Then when I do my measurement, I again measure 50% as z-spin-up and 50% as z-spin-down. These, however are not the same thing:
Suppose I reorient my Stern Gerlach apparatus to this time measure the x spin. To see what will happen you need the relations $$ |z_{UP}\rangle = \frac{1}{\sqrt{2}}(|x_{RIGHT}\rangle + |x_{LEFT}\rangle)$$ $$ |z_{DOWN}\rangle = \frac{1}{\sqrt{2}}(|x_{RIGHT}\rangle - |x_{LEFT}\rangle)$$ For the case where the incoming particles are in the z mixture, I'll get 50% x-spin-right and 50% x-spin-left.
For the superposition case though $$ \frac{1}{\sqrt{2}}(|z_{UP}\rangle + |z_{DOWN}\rangle)$$ $$=\frac{1}{\sqrt{2}} \{ \frac{1}{\sqrt{2}}(|x_{RIGHT}\rangle + |x_{LEFT}\rangle) + \frac{1}{\sqrt{2}}(|x_{RIGHT}\rangle - |x_{LEFT}\rangle)\}$$ $$=|x_{RIGHT}\rangle $$
So I'll get 100% x-spin-right.
In the coin example, we have a mixture, not a superposition. The reason macroscopic objects behave as mixtures rather than superpositions is generally explained by the phenomenon of decoherence.