In my opinion, one cannot rigorously [*] define the bracket. Suppose that you use the Dirac field equation for arriving to the ordinary Lagrangian density
$$
\mathcal{L} = c \bar{\psi} \left( i\hbar \gamma^\mu \frac{\partial}{\partial x^\mu} \right) \psi
$$
This is a function of the spinor components $\psi_i$ and their adjoints $\bar{\psi_i}$. The problem begins when you try to obtain the conjugate momentum for the adjoints (the dot denotes time derivative)
$$\bar{\pi_i} = \frac{\partial \mathcal{L}}{\partial \dot{\bar{\psi_i}}} = 0$$
which implies that not all the canonical variables are independent and not true 'phase-space' structure exists.
You could try to formally define Poisson brackets in the usual fashion,
$$
\{ A, B \}
\equiv
\sum_i
\frac{\partial A}{\partial \psi_i}
\frac{\partial B}{\partial \pi_i}
-
\frac{\partial A}{\partial \pi_i}
\frac{\partial B}{\partial \psi_i}
+
\sum_j
\frac{\partial A}{\partial \bar{\psi}_j}
\frac{\partial B}{\partial \bar{\pi}_j}
-
\frac{\partial A}{\partial \bar{\pi}_j}
\frac{\partial B}{\partial \bar{\psi}_j}
$$
but note that this is only formally valid, because the variables are not all independent. The equations of motion would be written somewhat as
$$
\dot{A}
\approx
\{ A, \mathcal{H} \}
$$
using Dirac weak equality sign, because this is a constrained dynamics. The Hamiltonian density is obtained from
$$
\mathcal{H}
\approx
\sum_i
\pi_i \dot{\psi}_i
+
\sum_j
\bar{\pi}_j \dot{\bar{\psi}}_j
-
\mathcal{L}
$$
Notice that all of this is a quantum treatment. There is not classical spinor theory.
[*] I suppose that all depends on what are you trying to do.