At least if $\vec v$ is really only a one dimensional parameter, measuring all the moments $\langle v^n \rangle_f$ seems to give me all the information to compute $\langle A \rangle_f$ with $A(v)$ being a function of $v$. So integer powers of the generator of the function algebra $v$ are special functions.
I wonder if there are other special functions whos expectation are equally useful and if so, how they depend of the system you consider. For example, let $\langle \dots \rangle_f$ be some prescrition to calculate a mean or expectation and
$$\langle A \rangle_f:=\int_\Gamma A(\vec v)\ f(\vec v)\ \text d \vec v,$$
then is there e.g. a statistical significance to $\langle f \rangle_f$?
Maybe this question has a "trivial" yes as answer, because there are more options than taylor series to give a basis for some function algebra of elements $f(v_1,v_2,\dots)$. However, I don't know how this changes if one considers noncomutative generators $[v_1,v_2]\ne0$.
The question comes in part because I'm intimidated by relations like
$$\langle T^n\rangle \equiv \int_0^\infty E^{n-1}\, e^{ - \left( {E /T } \right)^C }{\rm d}E\ = \tfrac{\Gamma \left(\tfrac{n }{ C }\right)}{C} \cdot T^n,$$
i.e. $\langle A(E) \rangle$ expectation values are apprearently trivial to compute for weights which are polynomial in functions $f_{\ T,C}(E)=e^{ - \left( {E /T } \right)^C}$.