It is hard to guess without seeing Gorillapod in use, but my guess would be the following:
Center of mass could be understood as an average position of the mass of the object. In order for an object to be in stable equilibrium, its center of muss must be vertically above the area, which is enclosed by contact points of tripod's legs with the ground. If you use elongated objects, center of mass is far from the point where camera is attached to the tripod and there is large likelihood that it won't be above the specified area, meaning that the tripod together with the object could fall over.
The point is that tripod is designed in a way that center of mass of the object it supports is fairly close to the attachment point, and of long lenses this is not so.