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There are quite a few nagging questions I have been having over the years, I do not require a full explanation, just some guidance in my assumptions and pointers if I am very wrong.

My basic knowledge of a lightbulb, is that the power dissipated by the tungsten filament heats it up to around 2,700–3,300K (inefficient!), emitting a yellow light. Something supporting my current (and next) claims is this image, see the bottom chart on temperatures:

enter image description here

With this, can I assert that fire is red (and yellow) due to the fact it is simply at those temperatures at where those colours are emitted, and it happens to emit those frequency photons? What is this called? I recall "thermionic emission" however, I am unsure if this relates closely to visible light as it does "heat".

Of course I've heard the phrase "white hot", iron (and other similar metals) melt at around 1800°K (tungsten at 3422°K), while that near-white temperature is below 10M°K! Not to mention it would glow green first before that blueish point. I will assert that metal cannot glow that hot - of course searching images of "white hot metal" come up with red-ish metal, however "white hot" is used often enough to cloud my memory.

"Colour temperature" is another confusing topic I have looked at, does it directly relate to the colour emitted at the above temperatures? I do not see "5000K" (often referenced as a blueish white) being white, unless other colours are combined, however how that is a "temperature" confuses me. Are they just separate from eachother?

I can also as a sanity check assume that some gas generated flames being blue, is due to the gas burning and not the temperature. Are all of my assumptions correct? Can you clarify or add anything?

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Related: physics.stackexchange.com/questions/4641/… –  kleingordon Mar 28 '12 at 0:09
    
The colors in that bar are merely there to confuse you - the scale I think actually refers to the upper bars (i.e. 100K is far below room temperature, things at that temperature are definitely not emitting a bright red.) Also note that it is a log scale - trying to get any quantitative data off of it is pointless. –  user2963 Mar 28 '12 at 0:18
    
The "Planckian Locus" image in the related question looks like something I'd want to look at. Will study what it is and how it was plotted when I can. Thank you two. –  Alexander Mar 28 '12 at 2:04
    
Are any factors at play here other than the temperature's peak frequency and the eye's RGB sensitivity? –  Griffin May 22 '13 at 4:50
    
@Griffin you only need emission spectrum and spectral sensitivity of eye cells. Check Wikipedia article on CIE 1931 color space, if you like. –  gigacyan May 22 '13 at 6:37

2 Answers 2

up vote 1 down vote accepted

Just to add to Vineet's answer. Wien's displacement law only tells you the peak wavelength of a hot object's spectrum. The actual emmission spectra is a broad function and so a hot object will emit both longer and shorter wavelengths.

Plank curve at diff temp

Remember also that a hot object will emit overall more power, and finally you have to include your eye's sensitivity to various wavelengths.

So a piece of hot metal will appear white because although it's peak emmission will be in the infrared it is still emitting a lot of power at shorter wavlengths and your eye is more sensitive to blue than red.

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Could you go into more detail (maybe with numbers) on how the spectrum/peak, augmented power, and eye's sensitivity results in a definite color? –  Griffin May 22 '13 at 4:40

A quick glance over you question, and it can be boiled down to 2 points,

1. What causes a material to glow?

2. What is the cause of a gas to glow in colored light even before reaching the required temperature as answered in 1.

The answer to 1. is known as blackbody radiation. Every body emits a characteristic spectrum of radiation at any temperature. This is given by Plank's law of blackbody radiation, Wien's displacement law and Stefan–Boltzmann law.

The important law here is displacement law, which states that, $$\lambda_{max}\propto \frac{1}{T} $$

Which means, as you increase the temperature of body, the frequency at which radiation is emitted will increase. So, a hotter body emits blue-er light as compared to a cooler body. But, since you are giving more energy via heating to that body, it will emit more radiation, it's just that higher frequency will have a larger contribution. Hence, the light will become whiter, with a bluish tinge.

Now, the second part, this phenomenon arise as an entirely different cause. This is called Emission Spectrum. This is caused because of electron transition to higher orbitals( because of heating them) and then spontaneous discharge to ground state by emitting a photon of equivalent frequency i.e. the difference between ground and exited state.$$h \nu = E_2 - E_1$$

EDIT1: As a side note, the image you have attached from wikimedia is largely misleading. The color as perceived by human is strictly restricted between 400nm to 700nm. Everything beyond this range is invisible to human eyes. The large red and blue color zone in the diagram is "made-up".

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