The answer for the question as posed is easy:
It could be either
This applies for the initial rate of heating. Of course, over time, the story is quite different. The temperature of the one in front of the AC could initially become higher than the one in the static room air. However, given sufficient time, of course the can in front of the AC will be the cooler can and will remain that way. Simple Newton's law of cooling:
$$\frac{dT_{can}}{dt} = C_{air} \left( T_{air} - T_{can} \right)$$
$$\frac{dT_{can}}{dt} = C_{AC} \left( T_{AC} - T_{can} \right)$$
The solution to both of these is simple. Written for both cases, they are:
$$T_{can}(t) = T_{air} - ( T_{air}-T_{can}(0)) exp(-C_{air} t)$$
$$T_{can}(t) = T_{AC} - ( T_{AC}-T_{can}(0)) exp(-C_{AC} t)$$
I can not make any statements about the exact values, and I don't think that's likely to be valuable for this exercise, but allow me to make simple relative statements.
$$ T_{air} > T_{AC}$$
$$C_{air} < C_{AC} $$
It's taken as a given that the initial can temperature is the same for both cases. Should the above inequalities have the same direction, then the problem would have an absolute answer. One can would be hotter at all times, $t>0$. In the problem presented, the signs are different leading to two possibilities, which is that the AC case initially leads to a higher temperature, or that the AC case is always of lower temperature. This can be formalized by the following inequality.
$$C_{AC} \left( T_{AC} - T_{can}(0) \right) \stackrel{?}{\le} C_{air} \left( T_{air} - T_{can}(0) \right)$$
If the above inequality is true, then the can in front of the AC is always a lower temperature. If it is false, then the can in front of the AC initially becomes hotter, then the other can becomes hotter.