Normally entropy is seen as an extensive thermodynamic coordinate, i.e. proportional to the mass of particles: Volume increases by considering a larger amount of gas in the "same state", while pressure will stay the same. So for simple systems entropy of a system that is a combination of 2 systems will be sum of individual entropies. Here it is less. This means that not the whole direct product of states of A and states of B is accessible to the combined system.
Consider a state space of 3x3 pixels for a particle A alone: 9 states. consider B to be an identical system: also 9 states. Now assume you can put A and B in the same 3x3 pixel space and allow them to also sit in the same pixel: 9x9=81 states, however suppose that they interact such that they can not sit in the same pixel:9x9 - 9=72 states so in this second example entropy is not additive for combination of systems. while it is in the first...