If the operators $X_i$ can be written as a sum of an annihilation and a creation part$^1$
$$X_i~=~A_i + A^{\dagger}_i, \qquad i~\in ~I, \tag{1}$$
$$\begin{align} A_i|\Omega\rangle~=~0, \qquad & \langle \Omega |A^{\dagger}_i~=~0, \cr
\qquad i~\in~&I,\end{align}\tag{2}$$
where
$$\begin{align} [A_i(t),A_j(t^{\prime})] ~=~& 0, \cr
[A^{\dagger}_i(t),A^{\dagger}_j(t^{\prime})] ~=~& 0, \cr i,j~\in ~&I,\end{align}\tag{3} $$
and
$$\begin{align} [A_i(t),A_j^\dagger(t^{\prime})]
~=~& (c~{\rm number}) \times {\bf 1},\cr i,j~\in~&I,\end{align}\tag{4} $$
i.e. proportional to the identity operator ${\bf 1}$, then one may prove that
$$\begin{align} T(&X_i(t)X_j(t^{\prime})) ~-~:X_i(t)X_j(t^{\prime}):\cr
~=~&\langle \Omega | T(X_i(t)X_j(t^{\prime}))|\Omega\rangle ~{\bf 1}.\end{align} \tag{5}$$
Proof of eq. (5): On one hand, the time ordering $T$ is defined as
$$\begin{align} T(&X_i(t)X_j(t^{\prime}))\cr
~=~& \Theta(t-t^{\prime}) X_i(t)X_j(t^{\prime})
+\Theta(t^{\prime}-t) X_j(t^{\prime})X_i(t)\cr
~=~&X_i(t)X_j(t^{\prime}) -\Theta(t^{\prime}-t) [X_i(t),X_j(t^{\prime})]\cr
~\stackrel{(1)+(3)}{=}&~X_i(t)X_j(t^{\prime})\cr &-\Theta(t^{\prime}-t) \left([A_i(t),A^{\dagger}_j(t^{\prime})]+[A^{\dagger}_i(t),A_j(t^{\prime})]\right).\end{align} \tag{6}$$
On the other hand, the normal ordering $::$ moves by definition the creation part to the left of the annihilation part, so that
$$\begin{align}:X_i(t)X_j(t^\prime):~\stackrel{(1)}{=}~& X_i(t)X_j(t^{\prime}) \cr
~-~& [A_i(t),A^{\dagger}_j(t^{\prime})], \end{align}\tag{7}$$
$$ \langle \Omega | :X_i(t)X_j(t^{\prime}):|\Omega\rangle~\stackrel{(1)+(2)}{=}~0.\tag{8}$$
The difference of eqs. (6) and (7) is the lhs. of eq. (5):
$$\begin{align} T(& X_i(t)X_j(t^{\prime})) ~-~:X_i(t)X_j(t^{\prime}): \cr
~\stackrel{(6)+(7)}{=}& \Theta(t-t^{\prime})[A_i(t),A^{\dagger}_j(t^{\prime})] \cr
~+~& \Theta(t^{\prime}-t)[A_j(t^{\prime}),A^{\dagger}_i(t)],\end{align}\tag{9}$$
which is proportional to the identity operator ${\bf 1}$ by assumption (4). Now sandwich eq. (9) between the bra $\langle \Omega |$ and the ket $|\Omega\rangle $. Since the rhs. of eq. (9) is proportional to the identity operator ${\bf 1}$, the unsandwiched rhs. must be equal to the sandwiched rhs. times the identity operator ${\bf 1}$. Hence also the unsandwiched lhs. of eq. (9) must also be equal to the sandwiched lhs. times the identity operator ${\bf 1}$. This yields eq. (5). $\Box$
A similar argument applied to eq. (7) yields that
$$\begin{align} X_i(t)&X_j(t^{\prime}) ~-~:X_i(t)X_j(t^{\prime}):\cr
~=~&\langle \Omega | X_i(t)X_j(t^{\prime})|\Omega\rangle ~{\bf 1} \end{align}\tag{10}$$
i.e. a version of eq. (5) without the time-order $T$.
--
$^1$ The operators $A_i$ and $A^{\dagger}_i$ need not be Hermitian conjugates in what follows. We implicitly assume that the vacuum $|\Omega\rangle$ is normalized: $\langle \Omega | \Omega\rangle=1$.